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- W4378515871 abstract "Abstract A two‐step sequential strategy involving a biocatalytic dehydrogenation/remote hydrofunctionalization, as a unified and versatile approach to selectively convert linear alkanes into a large array of valuable functionalized aliphatic derivatives is reported. The dehydrogenation is carried out by a mutant strain of a bacteria Rhodococcus and the produced alkenes are subsequently engaged in a remote functionalization through a metal‐catalyzed hydrometalation/migration sequence that subsequently react with a large variety of electrophiles. The judicious implementation of this combined biocatalytic and organometallic approach enabled us to develop a high‐yielding protocol to site‐selectively functionalize unreactive primary C−H bonds." @default.
- W4378515871 created "2023-05-28" @default.
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- W4378515871 date "2023-06-15" @default.
- W4378515871 modified "2023-09-25" @default.
- W4378515871 title "Selective Terminal Functionalization of Linear Alkanes**" @default.
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- W4378515871 doi "https://doi.org/10.1002/anie.202306343" @default.
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