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- W4378639025 abstract "Lanthanide coordination polymers (LCPs) have emerged as fascinating materials because of their specific structure and properties. In this work, utilizing hydrosoluble biomolecule of guanosine-5′-monophosphate (GMP) as bridging linker, lanthanide terbium ions (Tb3+) as metal nodes, and silver ions (Ag+) as sensitizers, we synthesized a pH responsive luminescent lanthanide CP probe of Tb/GMP/Ag. The probe possesses high luminescence due to the sensitization of Ag+; While in alkaline solutions, Ag+ in Tb/GMP/Ag immediately binds to OH−, forming Ag2O precipitation and resulting in a distinct fluorescence quenching of Tb/GMP/Ag. This probe displays high selectivity for OH− and a broader pH detection range of 7.5–13.0. In addition, based on the high anti-interference ability in serum, we applied Tb/GMP/Ag to measure pH in undiluted human serum samples, yielding satisfactory results." @default.
- W4378639025 created "2023-05-30" @default.
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- W4378639025 date "2017-03-01" @default.
- W4378639025 modified "2023-10-16" @default.
- W4378639025 title "Lanthanide coordination polymer probe for time-gated luminescence sensing of pH in undiluted human serum" @default.
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- W4378639025 doi "https://doi.org/10.1016/j.talanta.2016.07.028" @default.
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