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- W4378745243 endingPage "4182" @default.
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- W4378745243 abstract "A highly efficient, palladium-catalyzed glycosylation between 3,4-O-carbonate glycals and acid-labile oximes is disclosed. This approach features broad substrate scope, high functional group tolerance, and easy scalability, delivering glycosyl oximes in excellent yields with exclusive β-selectivity and retention of Z/E geometries. The power of this method is demonstrated by a set of site-selective transformations of glycosylation products and late-stage glycodiversification of bioactive molecules. Overall, our strategy provides an efficient toolkit for facile access to valuable N–O-linked glycosides." @default.
- W4378745243 created "2023-05-31" @default.
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- W4378745243 date "2023-05-30" @default.
- W4378745243 modified "2023-10-17" @default.
- W4378745243 title "Stereospecific Palladium-Catalyzed Direct Glycosylation of Oximes: Access to N–O-Linked Glycosides" @default.
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- W4378745243 doi "https://doi.org/10.1021/acs.orglett.3c01484" @default.
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