FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4378746668> ?p ?o ?g. }

• W4378746668 endingPage "4765" @default.
• W4378746668 startingPage "4760" @default.
• W4378746668 abstract "Transamidation of twistless (twist angle (τ) = 4.54°) and resonance stabilized N-pivaloyl activated amides is demonstrated in the absence of a catalyst, base and additive. Furthermore, C-N (1.374 Å) and CO (1.222 Å) bond lengths indicate the existence of amidic resonance; yet, transamidation is achieved at room temperature with alkyl amines in a short reaction time (0.5-2 h) with 60-97% yield. Amines bearing protic hydroxy and carboxylic acid groups were tolerated under the reaction conditions. Thus, our findings imply that N-pivaloyl-activated planar and resonance-stabilized amides are sufficiently reactive for nucleophilic addition." @default.
• W4378746668 created "2023-05-31" @default.
• W4378746668 creator A5035039964 @default.
• W4378746668 creator A5039859444 @default.
• W4378746668 date "2023-01-01" @default.
• W4378746668 modified "2023-10-17" @default.
• W4378746668 title "Amidic Resonance not a Barrier for Transamidation of N-Pivaloyl Activated Amides: Catalyst, Base and Additive Free Conditions" @default.
• W4378746668 cites W1981628074 @default.
• W4378746668 cites W2004549782 @default.
• W4378746668 cites W2045148055 @default.
• W4378746668 cites W2063925069 @default.
• W4378746668 cites W2502380854 @default.
• W4378746668 cites W2605351325 @default.
• W4378746668 cites W2623110373 @default.
• W4378746668 cites W2771189878 @default.
• W4378746668 cites W2785191358 @default.
• W4378746668 cites W2788051333 @default.
• W4378746668 cites W2791017562 @default.
• W4378746668 cites W2810801308 @default.
• W4378746668 cites W2890354423 @default.
• W4378746668 cites W2895194229 @default.
• W4378746668 cites W2897452107 @default.
• W4378746668 cites W2903589922 @default.
• W4378746668 cites W2908238357 @default.
• W4378746668 cites W2940656534 @default.
• W4378746668 cites W2946456358 @default.
• W4378746668 cites W2948902220 @default.
• W4378746668 cites W2952537206 @default.
• W4378746668 cites W2969375024 @default.
• W4378746668 cites W3000328060 @default.
• W4378746668 cites W3006001823 @default.
• W4378746668 cites W3024271652 @default.
• W4378746668 cites W3025479605 @default.
• W4378746668 cites W3033776216 @default.
• W4378746668 cites W3084317271 @default.
• W4378746668 cites W3168502219 @default.
• W4378746668 cites W3184404456 @default.
• W4378746668 cites W4220836112 @default.
• W4378746668 cites W4285496368 @default.
• W4378746668 cites W4294310600 @default.
• W4378746668 doi "https://doi.org/10.1039/d3ob00418j" @default.
• W4378746668 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37248856" @default.
• W4378746668 hasPublicationYear "2023" @default.
• W4378746668 type Work @default.
• W4378746668 citedByCount "0" @default.
• W4378746668 crossrefType "journal-article" @default.
• W4378746668 hasAuthorship W4378746668A5035039964 @default.
• W4378746668 hasAuthorship W4378746668A5039859444 @default.
• W4378746668 hasConcept C109214941 @default.
• W4378746668 hasConcept C121332964 @default.
• W4378746668 hasConcept C134121241 @default.
• W4378746668 hasConcept C134306372 @default.
• W4378746668 hasConcept C139210041 @default.
• W4378746668 hasConcept C155647269 @default.
• W4378746668 hasConcept C161790260 @default.
• W4378746668 hasConcept C178790620 @default.
• W4378746668 hasConcept C178907741 @default.
• W4378746668 hasConcept C185592680 @default.
• W4378746668 hasConcept C188027245 @default.
• W4378746668 hasConcept C191897082 @default.
• W4378746668 hasConcept C192562407 @default.
• W4378746668 hasConcept C2780263894 @default.
• W4378746668 hasConcept C33923547 @default.
• W4378746668 hasConcept C42058472 @default.
• W4378746668 hasConceptScore W4378746668C109214941 @default.
• W4378746668 hasConceptScore W4378746668C121332964 @default.
• W4378746668 hasConceptScore W4378746668C134121241 @default.
• W4378746668 hasConceptScore W4378746668C134306372 @default.
• W4378746668 hasConceptScore W4378746668C139210041 @default.
• W4378746668 hasConceptScore W4378746668C155647269 @default.
• W4378746668 hasConceptScore W4378746668C161790260 @default.
• W4378746668 hasConceptScore W4378746668C178790620 @default.
• W4378746668 hasConceptScore W4378746668C178907741 @default.
• W4378746668 hasConceptScore W4378746668C185592680 @default.
• W4378746668 hasConceptScore W4378746668C188027245 @default.
• W4378746668 hasConceptScore W4378746668C191897082 @default.
• W4378746668 hasConceptScore W4378746668C192562407 @default.
• W4378746668 hasConceptScore W4378746668C2780263894 @default.
• W4378746668 hasConceptScore W4378746668C33923547 @default.
• W4378746668 hasConceptScore W4378746668C42058472 @default.
• W4378746668 hasFunder F4320319346 @default.
• W4378746668 hasIssue "23" @default.
• W4378746668 hasLocation W43787466681 @default.
• W4378746668 hasLocation W43787466682 @default.
• W4378746668 hasOpenAccess W4378746668 @default.
• W4378746668 hasPrimaryLocation W43787466681 @default.
• W4378746668 hasRelatedWork W1965466195 @default.
• W4378746668 hasRelatedWork W2097014657 @default.
• W4378746668 hasRelatedWork W2324898221 @default.
• W4378746668 hasRelatedWork W2347114512 @default.
• W4378746668 hasRelatedWork W2395949388 @default.
• W4378746668 hasRelatedWork W2407764034 @default.
• W4378746668 hasRelatedWork W2604890884 @default.
• W4378746668 hasRelatedWork W2951317955 @default.
• W4378746668 hasRelatedWork W2952500419 @default.
• W4378746668 hasRelatedWork W2953235637 @default.
• W4378746668 hasVolume "21" @default.
• W4378746668 isParatext "false" @default.

• next