FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4378781696> ?p ?o ?g. }

• W4378781696 endingPage "17587" @default.
• W4378781696 startingPage "17577" @default.
• W4378781696 abstract "Designing efficient and durable bifunctional catalysts for 5-hydroxymethylfurfural (HMF) oxidation reaction (HMFOR) and hydrogen evolution reaction (HER) is desirable for the co-production of biomass-upgraded chemicals and sustainable hydrogen, which is limited by the competitive adsorption of hydroxyl species (OHads) and HMF molecules. Here, we report a class of Rh-O5/Ni(Fe) atomic site on nanoporous mesh-type layered double hydroxides with atomic-scale cooperative adsorption centers for highly active and stable alkaline HMFOR and HER catalysis. A low cell voltage of 1.48 V is required to achieve 100 mA cm-2 in an integrated electrolysis system along with excellent stability (>100 h). Operando infrared and X-ray absorption spectroscopic probes unveil that HMF molecules are selectively adsorbed and activated over the single-atom Rh sites and oxidized by in situ-formed electrophilic OHads species on neighboring Ni sites. Theoretical studies further demonstrate that the strong d-d orbital coupling interactions between atomic-level Rh and surrounding Ni atoms in the special Rh-O5/Ni(Fe) structure can greatly facilitate surface electronic exchange-and-transfer capabilities with the adsorbates (OHads and HMF molecules) and intermediates for efficient HMFOR and HER. We also reveal that the Fe sites in Rh-O5/Ni(Fe) structure can promote the electrocatalytic stability of the catalyst. Our findings provide new insights into catalyst design for complex reactions involving competitive adsorptions of multiple intermediates." @default.
• W4378781696 created "2023-06-01" @default.
• W4378781696 creator A5001237017 @default.
• W4378781696 creator A5001987994 @default.
• W4378781696 creator A5006454892 @default.
• W4378781696 creator A5007016148 @default.
• W4378781696 creator A5019108433 @default.
• W4378781696 creator A5022350148 @default.
• W4378781696 creator A5025689639 @default.
• W4378781696 creator A5028017378 @default.
• W4378781696 creator A5028121137 @default.
• W4378781696 creator A5037493153 @default.
• W4378781696 creator A5046844071 @default.
• W4378781696 creator A5048866141 @default.
• W4378781696 creator A5077976121 @default.
• W4378781696 creator A5090056849 @default.
• W4378781696 date "2023-05-30" @default.
• W4378781696 modified "2023-10-16" @default.
• W4378781696 title "Cooperative Rh-O₅/Ni(Fe) Site for Efficient Biomass Upgrading Coupled with H₂ Production" @default.
• W4378781696 cites W2115870645 @default.
• W4378781696 cites W2328832782 @default.
• W4378781696 cites W2522671493 @default.
• W4378781696 cites W2571531799 @default.
• W4378781696 cites W2766003229 @default.
• W4378781696 cites W2790507915 @default.
• W4378781696 cites W2885434353 @default.
• W4378781696 cites W2918625198 @default.
• W4378781696 cites W2936899030 @default.
• W4378781696 cites W2939140644 @default.
• W4378781696 cites W2947978899 @default.
• W4378781696 cites W2970759029 @default.
• W4378781696 cites W2974609736 @default.
• W4378781696 cites W2975772735 @default.
• W4378781696 cites W2983007138 @default.
• W4378781696 cites W2998506112 @default.
• W4378781696 cites W2999372363 @default.
• W4378781696 cites W3007042320 @default.
• W4378781696 cites W3010951050 @default.
• W4378781696 cites W3016537448 @default.
• W4378781696 cites W3023699510 @default.
• W4378781696 cites W3035407414 @default.
• W4378781696 cites W3079555704 @default.
• W4378781696 cites W3111341033 @default.
• W4378781696 cites W3111970177 @default.
• W4378781696 cites W3112139283 @default.
• W4378781696 cites W3122785574 @default.
• W4378781696 cites W3130478389 @default.
• W4378781696 cites W3158839207 @default.
• W4378781696 cites W3159468768 @default.
• W4378781696 cites W3162429781 @default.
• W4378781696 cites W3193975927 @default.
• W4378781696 cites W3200767026 @default.
• W4378781696 cites W3200876435 @default.
• W4378781696 cites W3206870157 @default.
• W4378781696 cites W4200272475 @default.
• W4378781696 cites W4206376053 @default.
• W4378781696 cites W4231105331 @default.
• W4378781696 cites W4247714682 @default.
• W4378781696 cites W4283784290 @default.
• W4378781696 cites W4294585844 @default.
• W4378781696 doi "https://doi.org/10.1021/jacs.3c02570" @default.
• W4378781696 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37253225" @default.
• W4378781696 hasPublicationYear "2023" @default.
• W4378781696 type Work @default.
• W4378781696 citedByCount "6" @default.
• W4378781696 countsByYear W43787816962023 @default.
• W4378781696 crossrefType "journal-article" @default.
• W4378781696 hasAuthorship W4378781696A5001237017 @default.
• W4378781696 hasAuthorship W4378781696A5001987994 @default.
• W4378781696 hasAuthorship W4378781696A5006454892 @default.
• W4378781696 hasAuthorship W4378781696A5007016148 @default.
• W4378781696 hasAuthorship W4378781696A5019108433 @default.
• W4378781696 hasAuthorship W4378781696A5022350148 @default.
• W4378781696 hasAuthorship W4378781696A5025689639 @default.
• W4378781696 hasAuthorship W4378781696A5028017378 @default.
• W4378781696 hasAuthorship W4378781696A5028121137 @default.
• W4378781696 hasAuthorship W4378781696A5037493153 @default.
• W4378781696 hasAuthorship W4378781696A5046844071 @default.
• W4378781696 hasAuthorship W4378781696A5048866141 @default.
• W4378781696 hasAuthorship W4378781696A5077976121 @default.
• W4378781696 hasAuthorship W4378781696A5090056849 @default.
• W4378781696 hasConcept C147789679 @default.
• W4378781696 hasConcept C150394285 @default.
• W4378781696 hasConcept C161790260 @default.
• W4378781696 hasConcept C163127949 @default.
• W4378781696 hasConcept C17525397 @default.
• W4378781696 hasConcept C178790620 @default.
• W4378781696 hasConcept C179104552 @default.
• W4378781696 hasConcept C185592680 @default.
• W4378781696 hasConcept C202189072 @default.
• W4378781696 hasConcept C2780443040 @default.
• W4378781696 hasConcept C32909587 @default.
• W4378781696 hasConcept C48940184 @default.
• W4378781696 hasConcept C50027330 @default.
• W4378781696 hasConcept C68801617 @default.
• W4378781696 hasConcept C75473681 @default.
• W4378781696 hasConceptScore W4378781696C147789679 @default.
• W4378781696 hasConceptScore W4378781696C150394285 @default.

• next