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• W4378783161 endingPage "8862" @default.
• W4378783161 startingPage "8846" @default.
• W4378783161 abstract "Treatment of the bis(chelate) complexes trans-[M(κ2-2-C6F4PPh2)2] (trans-1M; M = Ni, Pt) and cis-[Pt(κ2-2-C6F4PPh2)2] (cis-1Pt) with equimolar amounts or excess of PMe3 solution gave complexes of the type [(Me3P)xM(2-C6F4PPh2)2] (x = 2: 2Ma, 2Mb x = 1: 3Ma, 3Mb; M = Ni, Pt). The reactivity of complexes of the type 2M and 3M toward monovalent coinage metal ions (M′ = Cu, Ag, Au) was investigated next to the reaction of 1M toward [AuCl(PMe3)]. Four different complex types [(Me3P)2M(μ-2-C6F4PPh2)2M′Cl] (5MM′; M = Ni, Pt; M′ = Cu, Ag, Au), [(Me3P)M(κ2-2-C6F4PPh2)(μ-2-C6F4PPh2)M′Cl]x (x = 1: 6MM′; M = Pt; M′ = Cu, Au; x = 2: 6PtAg), head-to-tail-[(Me3P)ClM(μ-2-C6F4PPh2)2M′] (7MM′; M = Ni, Pt; M′ = Au), and head-to-head-[(Me3P)ClM(μ-2-C6F4PPh2)2M′] (8MM′; M = Ni, Pt; M′ = Cu, Ag, Au) were observed. Single-crystal X-ray analyses of complexes 5–8 revealed short metal–metal separations (2.7124(3)–3.3287(7) Å), suggestive of attractive metal–metal interactions. Quantum chemical calculations (atoms in molecules (AIM), electron localization function (ELF), non-covalent interaction (NCI), and natural bond orbital (NBO)) gave theoretical support that the interaction characteristics reach from a pure attractive non-covalent to an electron-shared (covalent) character." @default.
• W4378783161 created "2023-06-01" @default.
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• W4378783161 creator A5081153980 @default.
• W4378783161 date "2023-05-31" @default.
• W4378783161 modified "2023-09-26" @default.
• W4378783161 title "Formation of Heterobimetallic Complexes by Addition of d¹⁰-Metal Ions to [(Me₃P)_<i>x</i>M(2-C₆F₄PPh₂)₂] (<i>x</i> = 1, 2; M = Ni and Pt): A Synthetic and Computational Study of Metallophilic Interactions" @default.
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• W4378783161 doi "https://doi.org/10.1021/acs.inorgchem.3c00311" @default.
• W4378783161 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37254744" @default.
• W4378783161 hasPublicationYear "2023" @default.
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