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• W4378804116 abstract "The direct-current (DC) electrical conductivities (σ) of pelletized 70V2O5 ∙ 30TeO2 (mol%) glasses annealed in a H2 gas atmosphere at 473 K in the temperature range of 327–461 K were determined. Electrical conduction was explained using the Schnakenberg model, which is based on the log (σT)–T−1 relationship in the temperature region (T denotes the absolute temperature). The physical parameters (optical phonon frequency [ν0], hopping energy [WH], and disorder energy [WD]) determined using the model are as follows: ν0 = (1.15 ± 0.005–1.65 ± 0.005) × 1013 s−1, WH = 0.0722 ± 0.00005–0.296 ± 0.0005 eV, and WD = 0.0750 ± 0.00005–0.122 ± 0.0005 eV. The Schnakenberg model was suitable for interpreting the temperature dependence of the σ values in the temperature region based on these parameters. The electron-hopping distance (R) was calculated to be between 0.844 ± 0.058 and 3.71 ± 0.28 nm. The WH–R relationship showed that when the WH value decreased, the R value also decreased. WH and R indicate temperature-dependent values. This phenomenon was caused by electron hopping as a result of the following process: when the temperature decreased, the WH values decreased and the R values increased. These findings quantitatively demonstrate that a decrease in the temperature influences the alteration of the electrical conduction mechanism (from small polaron hopping to variable range hopping) by contributing to an increase in R and a decrease in WH." @default.
• W4378804116 created "2023-06-01" @default.
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• W4378804116 date "2023-09-01" @default.
• W4378804116 modified "2023-09-28" @default.
• W4378804116 title "Study of the electrical conduction mechanism of the 70V2O5 <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML altimg=si1.svg><mml:mrow><mml:mo>∙</mml:mo></mml:mrow></mml:math> 30TeO2 (mol%) pelletized glasses using the Schnakenberg model" @default.
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• W4378804116 doi "https://doi.org/10.1016/j.physb.2023.415020" @default.
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