FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4378840246> ?p ?o ?g. }

• W4378840246 abstract "•Synthesis and characterization of a terminal iron sulfide complex •Structural, spectroscopic, and computational support for Fe=S character •Dihydroanthracene oxidation reactivity analogous to terminal iron oxide complexes Iron-sulfur clusters are critical to a plethora of biological processes; however, little is known about the elementary unit of these clusters, namely, the [Fe=S]n+ fragment. Here, we report the synthesis and characterization of a terminal iron sulfido complex. Despite its high-spin (S = 5/2) ground state, structural, spectroscopic, and computational characterization provide evidence for iron sulfur multiple bond character. Intriguingly, the complex reacts with additional sulfur to afford an S = 3/2 iron(III) disulfido (S22−) complex. Preliminary studies reveal that the sulfido complex reacts with dihydroanthracene to afford an iron(II) hydrosulfido complex, akin to the reactivity of iron oxo complexes. By contrast, there is no reaction with the disulfido complex. These results provide important insight into the nature of the iron sulfide unit. Iron-sulfur clusters are critical to a plethora of biological processes; however, little is known about the elementary unit of these clusters, namely, the [Fe=S]n+ fragment. Here, we report the synthesis and characterization of a terminal iron sulfido complex. Despite its high-spin (S = 5/2) ground state, structural, spectroscopic, and computational characterization provide evidence for iron sulfur multiple bond character. Intriguingly, the complex reacts with additional sulfur to afford an S = 3/2 iron(III) disulfido (S22−) complex. Preliminary studies reveal that the sulfido complex reacts with dihydroanthracene to afford an iron(II) hydrosulfido complex, akin to the reactivity of iron oxo complexes. By contrast, there is no reaction with the disulfido complex. These results provide important insight into the nature of the iron sulfide unit." @default.
• W4378840246 created "2023-06-01" @default.
• W4378840246 creator A5000558729 @default.
• W4378840246 creator A5018106788 @default.
• W4378840246 creator A5038942615 @default.
• W4378840246 creator A5039945573 @default.
• W4378840246 creator A5041167652 @default.
• W4378840246 creator A5058367074 @default.
• W4378840246 creator A5079246484 @default.
• W4378840246 date "2023-05-01" @default.
• W4378840246 modified "2023-10-02" @default.
• W4378840246 title "Hydrogen atom abstraction by a high-spin [FeIII=S] complex" @default.
• W4378840246 cites W1966415697 @default.
• W4378840246 cites W1977476588 @default.
• W4378840246 cites W1980668806 @default.
• W4378840246 cites W1989277132 @default.
• W4378840246 cites W1994086113 @default.
• W4378840246 cites W1999582957 @default.
• W4378840246 cites W2007814348 @default.
• W4378840246 cites W2008488319 @default.
• W4378840246 cites W2013141514 @default.
• W4378840246 cites W2032366939 @default.
• W4378840246 cites W2048805796 @default.
• W4378840246 cites W2051509289 @default.
• W4378840246 cites W2066360040 @default.
• W4378840246 cites W2067930019 @default.
• W4378840246 cites W2071766178 @default.
• W4378840246 cites W2079023231 @default.
• W4378840246 cites W2090079874 @default.
• W4378840246 cites W2112721049 @default.
• W4378840246 cites W2120093870 @default.
• W4378840246 cites W2122862255 @default.
• W4378840246 cites W2135048467 @default.
• W4378840246 cites W2142722851 @default.
• W4378840246 cites W2145520044 @default.
• W4378840246 cites W2155066872 @default.
• W4378840246 cites W2206539669 @default.
• W4378840246 cites W2325573195 @default.
• W4378840246 cites W2326318157 @default.
• W4378840246 cites W2335053466 @default.
• W4378840246 cites W2411537103 @default.
• W4378840246 cites W2511805073 @default.
• W4378840246 cites W2603658745 @default.
• W4378840246 cites W2606294449 @default.
• W4378840246 cites W2757890639 @default.
• W4378840246 cites W2797914722 @default.
• W4378840246 cites W2945518216 @default.
• W4378840246 cites W2952261490 @default.
• W4378840246 cites W2985629046 @default.
• W4378840246 cites W3014641996 @default.
• W4378840246 cites W3035190513 @default.
• W4378840246 cites W3045932208 @default.
• W4378840246 cites W3081555856 @default.
• W4378840246 cites W3123548436 @default.
• W4378840246 cites W3204936379 @default.
• W4378840246 cites W3217267830 @default.
• W4378840246 cites W4200623428 @default.
• W4378840246 cites W4280580660 @default.
• W4378840246 cites W4308522399 @default.
• W4378840246 doi "https://doi.org/10.1016/j.chempr.2023.05.007" @default.
• W4378840246 hasPublicationYear "2023" @default.
• W4378840246 type Work @default.
• W4378840246 citedByCount "1" @default.
• W4378840246 countsByYear W43788402462023 @default.
• W4378840246 crossrefType "journal-article" @default.
• W4378840246 hasAuthorship W4378840246A5000558729 @default.
• W4378840246 hasAuthorship W4378840246A5018106788 @default.
• W4378840246 hasAuthorship W4378840246A5038942615 @default.
• W4378840246 hasAuthorship W4378840246A5039945573 @default.
• W4378840246 hasAuthorship W4378840246A5041167652 @default.
• W4378840246 hasAuthorship W4378840246A5058367074 @default.
• W4378840246 hasAuthorship W4378840246A5079246484 @default.
• W4378840246 hasConcept C142724271 @default.
• W4378840246 hasConcept C161790260 @default.
• W4378840246 hasConcept C171250308 @default.
• W4378840246 hasConcept C178790620 @default.
• W4378840246 hasConcept C185592680 @default.
• W4378840246 hasConcept C192562407 @default.
• W4378840246 hasConcept C204787440 @default.
• W4378840246 hasConcept C2776910235 @default.
• W4378840246 hasConcept C2777807490 @default.
• W4378840246 hasConcept C2778591166 @default.
• W4378840246 hasConcept C2780564542 @default.
• W4378840246 hasConcept C2780596425 @default.
• W4378840246 hasConcept C2780841128 @default.
• W4378840246 hasConcept C518881349 @default.
• W4378840246 hasConcept C71924100 @default.
• W4378840246 hasConcept C75473681 @default.
• W4378840246 hasConcept C8010536 @default.
• W4378840246 hasConceptScore W4378840246C142724271 @default.
• W4378840246 hasConceptScore W4378840246C161790260 @default.
• W4378840246 hasConceptScore W4378840246C171250308 @default.
• W4378840246 hasConceptScore W4378840246C178790620 @default.
• W4378840246 hasConceptScore W4378840246C185592680 @default.
• W4378840246 hasConceptScore W4378840246C192562407 @default.
• W4378840246 hasConceptScore W4378840246C204787440 @default.
• W4378840246 hasConceptScore W4378840246C2776910235 @default.
• W4378840246 hasConceptScore W4378840246C2777807490 @default.
• W4378840246 hasConceptScore W4378840246C2778591166 @default.
• W4378840246 hasConceptScore W4378840246C2780564542 @default.

• next