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- W4378906900 abstract "Abstract Herein we report an improved self‐assembling phosphorus ligand based on hydrogen bonding between pyridone/hydroxypyridine in the ligand backbone. The N ‐pyrrolyl substituents significantly improve the π‐backbonding properties of the ligand. Rhodium, iridium and platinum complexes of the ligand were prepared and analyzed by NMR spectroscopy and x‐ray crystal structure analysis. A catalyst based on this ligand showed very high catalytic activity and linear regioselectivity in rhodium‐catalyzed hydroformylation of 1‐octene. The same ligand was applied in linear regioselective iridium‐catalyzed hydroformylation of 1‐octene." @default.
- W4378906900 created "2023-06-01" @default.
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- W4378906900 date "2023-06-06" @default.
- W4378906900 modified "2023-09-25" @default.
- W4378906900 title "A Highly Active Hydroformylation Catalyst Using a Self‐Assembling <i>Bis</i>‐<i>N</i>‐Pyrrolyl Phosphine Ligand" @default.
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- W4378906900 doi "https://doi.org/10.1002/ajoc.202300244" @default.
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