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W4379335061 abstract "The activation of CH bonds has revolutionized modern synthetic chemistry. However, no general strategy for enantiospecific CH activation has been developed to date. We herein report an enantiospecific CH activation reaction followed by deuterium incorporation at stereogenic centers. Mechanistic studies suggest that the selectivity for the α-position of the directing heteroatom results from a four-membered dimetallacycle as the key intermediate. This work paves the way to novel molecular chemistry on nanoparticles." @default.
W4379335061 created "2023-06-05" @default.
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W4379335061 date "2015-08-14" @default.
W4379335061 modified "2023-10-16" @default.
W4379335061 title "Enantiospecific CH Activation Using Ruthenium Nanocatalysts" @default.
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W4379335061 doi "https://doi.org/10.1002/ange.201504554" @default.
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