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- W4379374878 abstract "Optically active [7]helicene-fused oxanorbornene polymers poly-1 were synthesized by ring-opening-metathesis polymerization (ROMP) of monomer 2, which was easily accessed by [4 + 2] cycloaddition of in situ-generated [7]helicenyl aryne and furan. The optical resolution of rac-2 using a chiral stationary phase afforded optically active (P)-2 and (M)-2. Of the various Grubbs catalysts tested, the first-generation one was found to be optimal for this ROMP. The chiroptical properties of the polymers were studied using circular dichroism and circularly polarized luminescence." @default.
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- W4379374878 date "2023-06-05" @default.
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- W4379374878 title "Synthesis and Properties of Optically Active [7]Helicene-Fused Oxanorbornene Polymers by Ring-Opening Metathesis" @default.
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- W4379374878 doi "https://doi.org/10.1021/acs.macromol.3c00588" @default.
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