Matches in SemOpenAlex for { <https://semopenalex.org/work/W4379618275> ?p ?o ?g. }
- W4379618275 endingPage "22149" @default.
- W4379618275 startingPage "22138" @default.
- W4379618275 abstract "Selective oxidation of active and inactive alcohol substrates and reduction of nitroarenes is a highly versatile conversion that remains a challenge in controlling functionality and adjustments in metal-organic frameworks (MOFs). On the other hand, it offers an attractive opportunity to expand their applications in designing the next generation of catalysts with improved performance. Herein, a novel mixed MOF consisting of supported 2-hydroxybenzamide (mixed MOF-salinidol) has been fabricated by post-synthetic modifications of mixed MOF. Subsequently, the prepared nanocomposites were modified to impart catalytic sites using palladium chloride ions mixed with MOF-salinidol/Pd (II). After successfully designing and structurally characterizing nanocomposites, we evaluated their activity in oxidizing primary and secondary alcohols using aerobic conditions with molecular oxygen and an air atmosphere. In addition, the stability of (mixed MOF-salinidol/Pd (II)) catalysts under catalytic conditions was also demonstrated by comparing the Fourier-transform infrared spectrum, scanning electron microscopy image, and ICP-OES method before and after catalysis. Based on the results, the active surface area of the synthesized nanocatalyst is large, which highlights its unique synergistic effect between post-synthetic modified MOF and Pd, and furthermore, the availability of catalytic sites from Pd, as demonstrated by outstanding catalytic activity." @default.
- W4379618275 created "2023-06-08" @default.
- W4379618275 creator A5014788186 @default.
- W4379618275 creator A5026223334 @default.
- W4379618275 creator A5041119331 @default.
- W4379618275 creator A5069880655 @default.
- W4379618275 creator A5076407137 @default.
- W4379618275 date "2023-06-07" @default.
- W4379618275 modified "2023-10-14" @default.
- W4379618275 title "Pd-Coordinated Salinidol-Modified Mixed MOF: An Excellent Active Center for Efficient Nitroarenes Reduction and Selective Oxidation of Alcohols" @default.
- W4379618275 cites W1968181991 @default.
- W4379618275 cites W2011080674 @default.
- W4379618275 cites W2035045721 @default.
- W4379618275 cites W2040145706 @default.
- W4379618275 cites W2043793709 @default.
- W4379618275 cites W2061366118 @default.
- W4379618275 cites W2062013694 @default.
- W4379618275 cites W2078054086 @default.
- W4379618275 cites W2079595598 @default.
- W4379618275 cites W2092349201 @default.
- W4379618275 cites W2107659960 @default.
- W4379618275 cites W2110993530 @default.
- W4379618275 cites W2124717850 @default.
- W4379618275 cites W2128680288 @default.
- W4379618275 cites W2129686018 @default.
- W4379618275 cites W2130283800 @default.
- W4379618275 cites W2152157407 @default.
- W4379618275 cites W2288710801 @default.
- W4379618275 cites W2318490343 @default.
- W4379618275 cites W2504285600 @default.
- W4379618275 cites W2556349240 @default.
- W4379618275 cites W2567277011 @default.
- W4379618275 cites W2596907290 @default.
- W4379618275 cites W2755243241 @default.
- W4379618275 cites W2759976531 @default.
- W4379618275 cites W2775137902 @default.
- W4379618275 cites W2800951191 @default.
- W4379618275 cites W2896738796 @default.
- W4379618275 cites W2898983779 @default.
- W4379618275 cites W2934887050 @default.
- W4379618275 cites W2936388882 @default.
- W4379618275 cites W2938467275 @default.
- W4379618275 cites W2939041730 @default.
- W4379618275 cites W2949645881 @default.
- W4379618275 cites W2966926866 @default.
- W4379618275 cites W2980791935 @default.
- W4379618275 cites W2991511342 @default.
- W4379618275 cites W2998755861 @default.
- W4379618275 cites W3015079749 @default.
- W4379618275 cites W3017162886 @default.
- W4379618275 cites W3021978373 @default.
- W4379618275 cites W3022863463 @default.
- W4379618275 cites W3034995587 @default.
- W4379618275 cites W3038059071 @default.
- W4379618275 cites W3043308287 @default.
- W4379618275 cites W3046667147 @default.
- W4379618275 cites W3082402545 @default.
- W4379618275 cites W3089462623 @default.
- W4379618275 cites W3094212385 @default.
- W4379618275 cites W3126538415 @default.
- W4379618275 cites W3127074851 @default.
- W4379618275 cites W3131079059 @default.
- W4379618275 cites W3161203850 @default.
- W4379618275 cites W3178288532 @default.
- W4379618275 cites W3181703056 @default.
- W4379618275 cites W3203671891 @default.
- W4379618275 cites W3210509956 @default.
- W4379618275 cites W4206433071 @default.
- W4379618275 cites W4206483310 @default.
- W4379618275 cites W4206700489 @default.
- W4379618275 cites W4214859584 @default.
- W4379618275 cites W4236555087 @default.
- W4379618275 cites W4306953368 @default.
- W4379618275 cites W4319761830 @default.
- W4379618275 cites W4327684948 @default.
- W4379618275 doi "https://doi.org/10.1021/acsomega.3c02414" @default.
- W4379618275 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37360424" @default.
- W4379618275 hasPublicationYear "2023" @default.
- W4379618275 type Work @default.
- W4379618275 citedByCount "7" @default.
- W4379618275 countsByYear W43796182752023 @default.
- W4379618275 crossrefType "journal-article" @default.
- W4379618275 hasAuthorship W4379618275A5014788186 @default.
- W4379618275 hasAuthorship W4379618275A5026223334 @default.
- W4379618275 hasAuthorship W4379618275A5041119331 @default.
- W4379618275 hasAuthorship W4379618275A5069880655 @default.
- W4379618275 hasAuthorship W4379618275A5076407137 @default.
- W4379618275 hasBestOaLocation W43796182751 @default.
- W4379618275 hasConcept C114157696 @default.
- W4379618275 hasConcept C127413603 @default.
- W4379618275 hasConcept C150394285 @default.
- W4379618275 hasConcept C15752686 @default.
- W4379618275 hasConcept C160892712 @default.
- W4379618275 hasConcept C161790260 @default.
- W4379618275 hasConcept C171250308 @default.
- W4379618275 hasConcept C178790620 @default.
- W4379618275 hasConcept C179104552 @default.
- W4379618275 hasConcept C179366358 @default.