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- W4379618402 abstract "Deuterated organic molecules have immense value in the pharmaceutical industry. Here, we present a synthetic strategy for direct trideuteromethylation of sulfenate ions derived in situ from β-sulfinyl esters in the presence of a base utilizing inexpensive and abundant CD3OTs as the electrophilic trideuteromethylating agent. This protocol provides straightforward access to an array of trideuteromethyl sulfoxides in yields of 75–92% with a high degree of deuteration. The ensuing trideuteromethyl sulfoxide can be readily modified into trideuteromethyl sulfone and sulfoximine." @default.
- W4379618402 created "2023-06-08" @default.
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- W4379618402 date "2023-06-07" @default.
- W4379618402 modified "2023-09-26" @default.
- W4379618402 title "Direct Trideuteromethylation of Sulfenate Anions Generated In Situ from β-Sulfinyl Esters: An Access to Trideuteromethyl Sulfoxides" @default.
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- W4379618402 doi "https://doi.org/10.1021/acs.joc.3c00573" @default.
- W4379618402 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37285517" @default.
- W4379618402 hasPublicationYear "2023" @default.
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