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- W4379768049 abstract "Lanthanide organic frameworks (Ln-MOFs) have attracted increasing research enthusiasm as photoluminescent materials. However, limited luminescence efficiency stemming from restricted energy transfer efficiency from the organic linker to the metal center hinders their applications. Herein, a uranyl sensitization approach was proposed to boost the luminescence efficiency of Ln-MOFs in a distinct heterobimetallic uranyl-europium organic framework. The record-breaking photoluminescence quantum yield (PLQY, 92.68%) among all reported Eu-MOFs was determined to benefit from nearly 100% energy transfer efficiency between UO22+ and Eu3+. Time-dependent density functional theory and ab initio wave-function theory calculations confirmed the overlap of excited state levels between UO22+ and Eu3+, which is responsible for the efficient energy transfer process. Coupled with intrinsically strong stopping power toward X-ray of the uranium center, SCU-UEu-2 features an ultralow detection limit of 1.243 μGyair/s, outperforming the commercial scintillator LYSO (13.257 μGyair/s) and satisfying the requirement of X-ray diagnosis (below 5.5 μGyair/s) in full." @default.
- W4379768049 created "2023-06-09" @default.
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- W4379768049 date "2023-06-08" @default.
- W4379768049 modified "2023-10-15" @default.
- W4379768049 title "Near-Unity Energy Transfer from Uranyl to Europium in a Heterobimetallic Organic Framework with Record-Breaking Quantum Yield" @default.
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- W4379768049 doi "https://doi.org/10.1021/jacs.3c01968" @default.
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- W4379768049 hasPublicationYear "2023" @default.
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