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- W4379966639 abstract "Linear π-conjugated oligopyrroles are attractive precursors for the synthesis of expanded porphyrinoids, chemosensors, and supramolecular motifs. We demonstrate a new method for the synthesis of a set of linear pyrrolyltripyrrins and dipyrrolyltripyrrins through a regioselective SNAr reaction on α,α′-dibromotripyrrins using various pyrroles or indoles. A representative calixsmaragdyrin was prepared via the 2-fold SNAr reaction between α,α′-dibromotripyrrin and dipyrromethene through a convergent [3 + 2] strategy. These oligopyrroles showed intense deep red absorptions with an interesting pH response." @default.
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- W4379966639 date "2023-06-09" @default.
- W4379966639 modified "2023-10-06" @default.
- W4379966639 title "Direct Access to Pyrrolyltripyrrins and Calixsmaragdyrin from S<sub>N</sub>Ar Reactions on α,α′-Dibromotripyrrins with Pyrroles or Indoles" @default.
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- W4379966639 doi "https://doi.org/10.1021/acs.orglett.3c01493" @default.
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