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- W4379980602 abstract "The synthesis of chiral triazole-fused pyrazine scaffolds from readily available substrates in a step-economical asymmetric catalytic way is highly appealing. We herein report that an efficient Cu/Ag relay catalyzed protocol employing cascade asymmetric propargylic amination, hydroazidation, and [3 + 2] cycloaddition reaction with high efficiency to access the target enantioenriched 1,2,3-triazolo[1,5-a]pyrazine has been accomplished by applying a novel N,N,P-ligand. The one-pot reaction of three components exhibits high functional group tolerance, excellent enantioselectivities, and a broad substrate scope with readily available starting materials." @default.
- W4379980602 created "2023-06-10" @default.
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- W4379980602 date "2023-06-09" @default.
- W4379980602 modified "2023-09-26" @default.
- W4379980602 title "Cu/Ag-Mediated One-Pot Enantioselective Synthesis of Fully Decorated 1,2,3-Triazolo[1,5-<i>a</i>]pyrazines" @default.
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- W4379980602 doi "https://doi.org/10.1021/acs.orglett.3c01524" @default.
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