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- W4380028529 abstract "Photocatalytic 2-iodoethanol (IEO) coupling provides 1,4-butanediol (BDO) of particular interest to produce degradable polyesters. However, the reduction potential of IEO is too negative (−1.9 vs NHE) to be satisfied by most of the semiconductors, and the kinetics of transferring one electron for IEO coupling is slow. Here we design a catalytic Ni complex, which works synergistically with TiO2, realizing reductive coupling of IEO powered by photo-energy. Coordinating by terpyridine stabilizes Ni2+ from being photo-deposited to TiO2, thereby retaining the steric configuration beneficial for IEO coupling. The Ni complex can rapidly extract electrons from TiO2, generating a low-valent Ni capable of reducing IEO. The photocatalytic IEO coupling thus provides BDO in 72 % selectivity. By a stepwise procedure, BDO is obtained with 70 % selectivity from ethylene glycol. This work put forward a strategy for the photocatalytic reduction of molecules requiring strong negative potential." @default.
- W4380028529 created "2023-06-10" @default.
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- W4380028529 date "2023-06-23" @default.
- W4380028529 modified "2023-10-16" @default.
- W4380028529 title "Photocatalytic 2‐Iodoethanol Coupling to Produce 1,4‐Butanediol Mediated by TiO<sub>2</sub> and a Catalytic Nickel Complex" @default.
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- W4380028529 doi "https://doi.org/10.1002/ange.202301668" @default.
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