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- W4380083668 abstract "We communicate a general method for the syntheses of acenaphthene-fused imidazolinium salts that are direct precursors to augmented N-heterocyclic carbenes with a fixed cis geometry. Reduction of bis(imino)acenaphthene ligands with a LiAlH4/AlCl3 reagent mix initially produced the corresponding 1,2-diamines which, upon ring-closing reaction with triethyl orthoformate in acidic solution, gave the requisite ionic intermediates. Formation of the carbenes was then shown by preparation of selected [Cu(NHC)] complexes that were obtained via treatment of the respective imidazolinium salt with base in the presence of a Cu(I) source." @default.
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- W4380083668 date "2023-06-09" @default.
- W4380083668 modified "2023-09-25" @default.
- W4380083668 title "General Access to Acenaphthene-Fused <i>N</i>-Heterocyclic Carbene Ligands" @default.
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- W4380083668 doi "https://doi.org/10.1021/acs.organomet.3c00189" @default.
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