FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4380087593> ?p ?o ?g. }

• W4380087593 abstract "Cu-exchanged mordenite (MOR) is a promising material for partial CH4 oxidation. The structural diversity of Cu species within MOR makes it difficult to identify the active Cu sites and to determine their redox and kinetic properties. In this study, the Cu speciation in Cu-MOR materials with different Cu loadings has been determined using operando electron paramagnetic resonance (EPR) and operando ultraviolet-visible (UV/Vis) spectroscopy as well as in situ photoluminescence (PL) and Fourier-transform infrared (FTIR) spectroscopy. A novel pathway for CH4 oxidation involving paired [CuOH]+ and bare Cu2+ species has been identified. The reduction of bare Cu2+ ions facilitated by adjacent [CuOH]+ demonstrates that the frequently reported assumption of redox-inert Cu2+ centers does not generally apply. The measured site-specific reaction kinetics show that dimeric Cu species exhibit a faster reaction rate and a higher apparent activation energy than monomeric Cu2+ active sites highlighting their difference in the CH4 oxidation potential." @default.
• W4380087593 created "2023-06-10" @default.
• W4380087593 creator A5010083603 @default.
• W4380087593 creator A5013565453 @default.
• W4380087593 creator A5021072920 @default.
• W4380087593 creator A5045814455 @default.
• W4380087593 creator A5054120563 @default.
• W4380087593 creator A5092129651 @default.
• W4380087593 date "2023-07-11" @default.
• W4380087593 modified "2023-09-25" @default.
• W4380087593 title "Methane Oxidation over Cu²⁺/[CuOH]⁺ Pairs and Site‐Specific Kinetics in Copper Mordenite Revealed by Operando Electron Paramagnetic Resonance and UV/Visible Spectroscopy" @default.
• W4380087593 cites W1963817209 @default.
• W4380087593 cites W1988726984 @default.
• W4380087593 cites W1990385937 @default.
• W4380087593 cites W2002612078 @default.
• W4380087593 cites W2023873499 @default.
• W4380087593 cites W2041721340 @default.
• W4380087593 cites W2062976687 @default.
• W4380087593 cites W2063910422 @default.
• W4380087593 cites W2064576885 @default.
• W4380087593 cites W2065096377 @default.
• W4380087593 cites W2067683064 @default.
• W4380087593 cites W2077554212 @default.
• W4380087593 cites W2087957469 @default.
• W4380087593 cites W2091875583 @default.
• W4380087593 cites W2101309960 @default.
• W4380087593 cites W2102618078 @default.
• W4380087593 cites W2216852268 @default.
• W4380087593 cites W2285384451 @default.
• W4380087593 cites W2317635331 @default.
• W4380087593 cites W2331707417 @default.
• W4380087593 cites W2523814907 @default.
• W4380087593 cites W2567556848 @default.
• W4380087593 cites W2581039322 @default.
• W4380087593 cites W2770976699 @default.
• W4380087593 cites W2803376014 @default.
• W4380087593 cites W2809928134 @default.
• W4380087593 cites W2920899382 @default.
• W4380087593 cites W2922157415 @default.
• W4380087593 cites W2933626243 @default.
• W4380087593 cites W2949170561 @default.
• W4380087593 cites W2951515259 @default.
• W4380087593 cites W2983616395 @default.
• W4380087593 cites W3001929705 @default.
• W4380087593 cites W3007650050 @default.
• W4380087593 cites W3014355341 @default.
• W4380087593 cites W3112781426 @default.
• W4380087593 cites W3120741794 @default.
• W4380087593 cites W3152748943 @default.
• W4380087593 cites W3159700292 @default.
• W4380087593 cites W3165904487 @default.
• W4380087593 cites W3167321450 @default.
• W4380087593 cites W3181080923 @default.
• W4380087593 cites W3203299747 @default.
• W4380087593 cites W4214859180 @default.
• W4380087593 cites W4304208647 @default.
• W4380087593 doi "https://doi.org/10.1002/ange.202303574" @default.
• W4380087593 hasPublicationYear "2023" @default.
• W4380087593 type Work @default.
• W4380087593 citedByCount "0" @default.
• W4380087593 crossrefType "journal-article" @default.
• W4380087593 hasAuthorship W4380087593A5010083603 @default.
• W4380087593 hasAuthorship W4380087593A5013565453 @default.
• W4380087593 hasAuthorship W4380087593A5021072920 @default.
• W4380087593 hasAuthorship W4380087593A5045814455 @default.
• W4380087593 hasAuthorship W4380087593A5054120563 @default.
• W4380087593 hasAuthorship W4380087593A5092129651 @default.
• W4380087593 hasBestOaLocation W43800875931 @default.
• W4380087593 hasConcept C113196181 @default.
• W4380087593 hasConcept C121332964 @default.
• W4380087593 hasConcept C147789679 @default.
• W4380087593 hasConcept C148898269 @default.
• W4380087593 hasConcept C160892712 @default.
• W4380087593 hasConcept C178790620 @default.
• W4380087593 hasConcept C179104552 @default.
• W4380087593 hasConcept C185592680 @default.
• W4380087593 hasConcept C187961010 @default.
• W4380087593 hasConcept C32891209 @default.
• W4380087593 hasConcept C43617362 @default.
• W4380087593 hasConcept C46141821 @default.
• W4380087593 hasConcept C544778455 @default.
• W4380087593 hasConcept C55904794 @default.
• W4380087593 hasConcept C62520636 @default.
• W4380087593 hasConcept C75473681 @default.
• W4380087593 hasConcept C95121573 @default.
• W4380087593 hasConceptScore W4380087593C113196181 @default.
• W4380087593 hasConceptScore W4380087593C121332964 @default.
• W4380087593 hasConceptScore W4380087593C147789679 @default.
• W4380087593 hasConceptScore W4380087593C148898269 @default.
• W4380087593 hasConceptScore W4380087593C160892712 @default.
• W4380087593 hasConceptScore W4380087593C178790620 @default.
• W4380087593 hasConceptScore W4380087593C179104552 @default.
• W4380087593 hasConceptScore W4380087593C185592680 @default.
• W4380087593 hasConceptScore W4380087593C187961010 @default.
• W4380087593 hasConceptScore W4380087593C32891209 @default.
• W4380087593 hasConceptScore W4380087593C43617362 @default.
• W4380087593 hasConceptScore W4380087593C46141821 @default.
• W4380087593 hasConceptScore W4380087593C544778455 @default.
• W4380087593 hasConceptScore W4380087593C55904794 @default.
• W4380087593 hasConceptScore W4380087593C62520636 @default.

• next