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- W4380201002 abstract "Thermal conductivity of polymer composites with oriented anisotropic fillers is commonly predicted based on the simplified cuboid unit-cell models. However, the models are too simple to reveal the real thermal conductivity of composites without absolutely aligned fillers. Here, a super-cell model with offset fillers based on a hexagonal prism primitive-cell after considering shape factor [Chem. Eng. J. 2022, 441, 136104.] is established to predict thermal conductivity as close to reality as possible for polymer composites with oriented fibrous, wirelike, and flake fillers. The impact of shape factor, fillers’ intrinsic thermal conductivity, size and loading, polymer's intrinsic thermal conductivity, and thermal interface resistance between polymer and fillers, on the anisotropic thermal conductivity of polymer composites are systematically evaluated by performing finite element numerical simulation. The model is applied to predict the anisotropic thermal conductivity of polymer based highly through-plane thermally conductive thermal interface materials, and highly in-plane thermally conductive thermal diffusion materials, which are in excellent agreement with the experimental ones. This work not only provides a practical means to predict the thermal conductivity of the oriented anisotropic fillers /polymer composites, but also has the guiding significance for designing thermal management materials." @default.
- W4380201002 created "2023-06-11" @default.
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- W4380201002 date "2023-11-01" @default.
- W4380201002 modified "2023-10-18" @default.
- W4380201002 title "Offset supper-cell model of polymer composites with oriented anisotropic fillers for thermal conductivity prediction considering shape factor" @default.
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- W4380201002 doi "https://doi.org/10.1016/j.ijheatmasstransfer.2023.124373" @default.
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