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- W4380355870 endingPage "9791" @default.
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- W4380355870 abstract "Lanthanide luminescent MOF materials show excellent luminescent properties. However, obtaining lanthanide luminescent MOFs with high quantum yield is a challenging research. A novel bismuth-based metal-organic framework [Bi(SIP)(DMF)2] was constructed by solvothermal method, utilizing 5-sulfoisophthalic acid monosodium salt (NaH2SIP) and Bi(NO3)3·5H2O. Thereafter, doped MOFs (Ln-Bi-SIP, Ln = Eu, Tb, Sm, Dy, Yb, Nd, Er) with different luminescent properties have been obtained by in situ doping with different lanthanide metal ions, among which Eu-Bi-SIP, Tb-Bi-SIP, Sm-Bi-SIP, and Dy-Bi-SIP have high quantum yield. What is special is that the doping amount of Ln3+ ions is very low, and the doped MOF can achieve high luminescence quantum yields. EuTb-Bi-SIP obtained by Eu3+/Tb3+ codoping and Dy-Bi-SIP exhibit good temperature sensing performance over a wide temperature range with the maximum sensitivity Sr of 1.6%·K-1 (433 K) and 2.6%·K-1, respectively (133 K), while the cycling experiments also show good repeatability in the assay temperature range. Finally, considering the practical application value, EuTb-Bi-SIP was blended with an organic polymer poly(methyl methacrylate) (PMMA) to produce a thin film, which shows different color changes at different temperatures." @default.
- W4380355870 created "2023-06-13" @default.
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- W4380355870 date "2023-06-12" @default.
- W4380355870 modified "2023-10-16" @default.
- W4380355870 title "Construction of High Quantum Yield Lanthanide Luminescent MOF Platform by In Situ Doping and Its Temperature Sensing Performance" @default.
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- W4380355870 doi "https://doi.org/10.1021/acs.inorgchem.3c00498" @default.
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