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- W4380589301 abstract "We report a photocatalytic strategy for selective reduction of nitroarenes to azoxy-, azo- and hydrazo-compounds catalyzed by bismuth porphyrin metal organic framework (Bi-MOF) through controlling time, atmosphere, or the quantity of NaBH4 under mild conditions (Rt, Light). The photocatalytic protocol exhibited excellent functional group compatibility, and the recyclability of Bi-MOF was demonstrated by five cycle tests. More importantly, the scale-up experiment of 10 g can also be carried out smoothly with excellent yield of 95%. This green and effective photocatalytic strategy provides a practical possibility for the large-scale synthesis of azo intermediates." @default.
- W4380589301 created "2023-06-15" @default.
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- W4380589301 date "2023-07-17" @default.
- W4380589301 modified "2023-10-11" @default.
- W4380589301 title "Light‐promoted Selective Reduction of Nitroarenes to Azoxy‐, Azo‐ and Hydrazo‐compounds Catalyzed by Bismuth Porphyrin Metal Organic Framework" @default.
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- W4380589301 doi "https://doi.org/10.1002/adsc.202300239" @default.
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