Matches in SemOpenAlex for { <https://semopenalex.org/work/W4380882005> ?p ?o ?g. }
- W4380882005 abstract "Abstract Herein, we described the first synthesis of the pentasaccharide and decasaccharide of the A. baumannii ATCC 17961 O‐antigen for developing a synthetic carbohydrate‐based vaccine against A. baumannii infection. The efficient synthesis of the rare sugar 2,3‐diacetamido‐glucuronate was achieved using our recently introduced organocatalytic glycosylation method. We found, for the first time, that long‐range levulinoyl group participation via a hydrogen bond can result in a significantly improved β‐selectivity in glycosylations. This solves the stereoselectivity problem of highly branched galactose acceptors. The proposed mechanism was supported by control experiments and DFT computations. Benefiting from the long‐range levulinoyl group participation strategy, the pentasaccharide donor and acceptor were obtained via an efficient [2+1+2] one‐pot glycosylation method and were used for the target decasaccharide synthesis." @default.
- W4380882005 created "2023-06-17" @default.
- W4380882005 creator A5007293606 @default.
- W4380882005 creator A5011121799 @default.
- W4380882005 creator A5017608631 @default.
- W4380882005 creator A5023536935 @default.
- W4380882005 creator A5028870837 @default.
- W4380882005 creator A5031246359 @default.
- W4380882005 creator A5044301848 @default.
- W4380882005 creator A5045499555 @default.
- W4380882005 creator A5058602846 @default.
- W4380882005 creator A5064699998 @default.
- W4380882005 creator A5080516185 @default.
- W4380882005 creator A5085547697 @default.
- W4380882005 date "2023-07-10" @default.
- W4380882005 modified "2023-10-17" @default.
- W4380882005 title "Stereoselective Synthesis of the O‐antigen of <i>A. baumannii</i> ATCC 17961 Using Long‐Range Levulinoyl Group Participation" @default.
- W4380882005 cites W1964611885 @default.
- W4380882005 cites W1970998174 @default.
- W4380882005 cites W2016729959 @default.
- W4380882005 cites W2019689700 @default.
- W4380882005 cites W2049225087 @default.
- W4380882005 cites W2061276449 @default.
- W4380882005 cites W2069913189 @default.
- W4380882005 cites W2089392594 @default.
- W4380882005 cites W2120193168 @default.
- W4380882005 cites W2122063199 @default.
- W4380882005 cites W2148309734 @default.
- W4380882005 cites W2159435953 @default.
- W4380882005 cites W2163150937 @default.
- W4380882005 cites W2192841249 @default.
- W4380882005 cites W2317979482 @default.
- W4380882005 cites W2322637803 @default.
- W4380882005 cites W2618318713 @default.
- W4380882005 cites W2621789448 @default.
- W4380882005 cites W2751458705 @default.
- W4380882005 cites W2782216877 @default.
- W4380882005 cites W2786649997 @default.
- W4380882005 cites W2790006937 @default.
- W4380882005 cites W2808778957 @default.
- W4380882005 cites W2811511919 @default.
- W4380882005 cites W2884630597 @default.
- W4380882005 cites W2889291148 @default.
- W4380882005 cites W2898852740 @default.
- W4380882005 cites W2942621659 @default.
- W4380882005 cites W2948575476 @default.
- W4380882005 cites W2963957908 @default.
- W4380882005 cites W2970715612 @default.
- W4380882005 cites W2989745899 @default.
- W4380882005 cites W2989852135 @default.
- W4380882005 cites W2995491240 @default.
- W4380882005 cites W2999169037 @default.
- W4380882005 cites W3000236050 @default.
- W4380882005 cites W3004479313 @default.
- W4380882005 cites W3018324453 @default.
- W4380882005 cites W3038902560 @default.
- W4380882005 cites W3046879974 @default.
- W4380882005 cites W3061602042 @default.
- W4380882005 cites W3086477288 @default.
- W4380882005 cites W3115425319 @default.
- W4380882005 cites W3138255961 @default.
- W4380882005 cites W3144656847 @default.
- W4380882005 cites W3166284612 @default.
- W4380882005 cites W3197085163 @default.
- W4380882005 cites W3197421632 @default.
- W4380882005 cites W3197635017 @default.
- W4380882005 cites W3206317921 @default.
- W4380882005 cites W3212675169 @default.
- W4380882005 cites W4244558397 @default.
- W4380882005 cites W4280541526 @default.
- W4380882005 cites W4282938977 @default.
- W4380882005 cites W4283159761 @default.
- W4380882005 cites W4292769252 @default.
- W4380882005 cites W4310497400 @default.
- W4380882005 cites W4311635577 @default.
- W4380882005 cites W4318253720 @default.
- W4380882005 cites W4318928373 @default.
- W4380882005 doi "https://doi.org/10.1002/ange.202306971" @default.
- W4380882005 hasPublicationYear "2023" @default.
- W4380882005 type Work @default.
- W4380882005 citedByCount "0" @default.
- W4380882005 crossrefType "journal-article" @default.
- W4380882005 hasAuthorship W4380882005A5007293606 @default.
- W4380882005 hasAuthorship W4380882005A5011121799 @default.
- W4380882005 hasAuthorship W4380882005A5017608631 @default.
- W4380882005 hasAuthorship W4380882005A5023536935 @default.
- W4380882005 hasAuthorship W4380882005A5028870837 @default.
- W4380882005 hasAuthorship W4380882005A5031246359 @default.
- W4380882005 hasAuthorship W4380882005A5044301848 @default.
- W4380882005 hasAuthorship W4380882005A5045499555 @default.
- W4380882005 hasAuthorship W4380882005A5058602846 @default.
- W4380882005 hasAuthorship W4380882005A5064699998 @default.
- W4380882005 hasAuthorship W4380882005A5080516185 @default.
- W4380882005 hasAuthorship W4380882005A5085547697 @default.
- W4380882005 hasConcept C161790260 @default.
- W4380882005 hasConcept C178790620 @default.
- W4380882005 hasConcept C181647583 @default.
- W4380882005 hasConcept C185592680 @default.
- W4380882005 hasConcept C21951064 @default.
- W4380882005 hasConcept C2777313579 @default.