FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4381112811> ?p ?o ?g. }

• W4381112811 endingPage "855" @default.
• W4381112811 startingPage "846" @default.
• W4381112811 abstract "Abstract Chiral materials with strong linear anisotropies are difficult to accurately characterize with circular dichroism (CD) because of artifactual contributions to their spectra from linear dichroism (LD) and birefringence (LB). Historically, researchers have used a second‐order Taylor series expansion on the Mueller matrix to model the LDLB interaction effects on the spectra in conventional materials, but this approach may no longer be sufficient to account for the artifactual CD signals in emergent materials. In this work, we present an expression to model the measured CD using a third‐order expansion, which introduces “pairwise interference” terms that, unlike the LDLB terms, cannot be averaged out of the signal. We find that the third‐order pairwise interference terms can make noticeable contributions to the simulated CD spectra. Using numerical simulations of the measured CD across a broad range of linear and chiral anisotropy parameters, the LDLB interactions are most prominent in samples that have strong linear anisotropies (LD, LB) but negligible chiral anisotropies, where the measured CD strays from the chirality‐induced CD by factors greater than 10 3 . Additionally, the pairwise interactions are most significant in systems with moderate‐to‐strong chiral and linear anisotropies, where the measured CD is inflated twofold, a figure that grows as linear anisotropies approach their maximum. In summary, media with moderate‐to‐strong linear anisotropy are in great danger of having their CD altered by these effects in subtle manners. This work highlights the significance of considering distortions in CD measurements through higher‐order pairwise interference effects in highly anisotropic nanomaterials." @default.
• W4381112811 created "2023-06-19" @default.
• W4381112811 creator A5013115261 @default.
• W4381112811 creator A5084302687 @default.
• W4381112811 creator A5089195757 @default.
• W4381112811 date "2023-06-18" @default.
• W4381112811 modified "2023-10-14" @default.
• W4381112811 title "Can we still measure circular dichroism with circular dichroism spectrometers: The dangers of anisotropic artifacts" @default.
• W4381112811 cites W1568042294 @default.
• W4381112811 cites W1631089133 @default.
• W4381112811 cites W1968644540 @default.
• W4381112811 cites W1978991229 @default.
• W4381112811 cites W1983717339 @default.
• W4381112811 cites W1991619985 @default.
• W4381112811 cites W2023858770 @default.
• W4381112811 cites W2024607050 @default.
• W4381112811 cites W2029619212 @default.
• W4381112811 cites W2033606217 @default.
• W4381112811 cites W2038333089 @default.
• W4381112811 cites W2042460881 @default.
• W4381112811 cites W2050051207 @default.
• W4381112811 cites W2051723371 @default.
• W4381112811 cites W2057898224 @default.
• W4381112811 cites W2076359110 @default.
• W4381112811 cites W2083256985 @default.
• W4381112811 cites W2089155137 @default.
• W4381112811 cites W2109352018 @default.
• W4381112811 cites W2128542552 @default.
• W4381112811 cites W2133785712 @default.
• W4381112811 cites W2140308971 @default.
• W4381112811 cites W2147484108 @default.
• W4381112811 cites W2162859113 @default.
• W4381112811 cites W2501561368 @default.
• W4381112811 cites W2604722209 @default.
• W4381112811 cites W2667171935 @default.
• W4381112811 cites W2806833831 @default.
• W4381112811 cites W2938201756 @default.
• W4381112811 cites W2945862649 @default.
• W4381112811 cites W2945911360 @default.
• W4381112811 cites W2950510345 @default.
• W4381112811 cites W3040653554 @default.
• W4381112811 cites W3083213360 @default.
• W4381112811 cites W3083248751 @default.
• W4381112811 cites W3124310860 @default.
• W4381112811 cites W3183890717 @default.
• W4381112811 cites W3203042534 @default.
• W4381112811 cites W3204666660 @default.
• W4381112811 cites W4200453813 @default.
• W4381112811 cites W4220757271 @default.
• W4381112811 cites W4295132158 @default.
• W4381112811 cites W4309231167 @default.
• W4381112811 cites W4309360930 @default.
• W4381112811 cites W4318156771 @default.
• W4381112811 doi "https://doi.org/10.1002/chir.23597" @default.
• W4381112811 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37331723" @default.
• W4381112811 hasPublicationYear "2023" @default.
• W4381112811 type Work @default.
• W4381112811 citedByCount "0" @default.
• W4381112811 crossrefType "journal-article" @default.
• W4381112811 hasAuthorship W4381112811A5013115261 @default.
• W4381112811 hasAuthorship W4381112811A5084302687 @default.
• W4381112811 hasAuthorship W4381112811A5089195757 @default.
• W4381112811 hasConcept C10138342 @default.
• W4381112811 hasConcept C105600476 @default.
• W4381112811 hasConcept C105795698 @default.
• W4381112811 hasConcept C120665830 @default.
• W4381112811 hasConcept C121332964 @default.
• W4381112811 hasConcept C124668440 @default.
• W4381112811 hasConcept C125743686 @default.
• W4381112811 hasConcept C127162648 @default.
• W4381112811 hasConcept C133571119 @default.
• W4381112811 hasConcept C146593782 @default.
• W4381112811 hasConcept C162324750 @default.
• W4381112811 hasConcept C182306322 @default.
• W4381112811 hasConcept C184898388 @default.
• W4381112811 hasConcept C185592680 @default.
• W4381112811 hasConcept C20621625 @default.
• W4381112811 hasConcept C2780009758 @default.
• W4381112811 hasConcept C30475298 @default.
• W4381112811 hasConcept C32022120 @default.
• W4381112811 hasConcept C33923547 @default.
• W4381112811 hasConcept C41008148 @default.
• W4381112811 hasConcept C41999313 @default.
• W4381112811 hasConcept C4839761 @default.
• W4381112811 hasConcept C52703039 @default.
• W4381112811 hasConcept C62520636 @default.
• W4381112811 hasConcept C7602139 @default.
• W4381112811 hasConcept C76155785 @default.
• W4381112811 hasConcept C77088390 @default.
• W4381112811 hasConcept C8010536 @default.
• W4381112811 hasConcept C85725439 @default.
• W4381112811 hasConceptScore W4381112811C10138342 @default.
• W4381112811 hasConceptScore W4381112811C105600476 @default.
• W4381112811 hasConceptScore W4381112811C105795698 @default.
• W4381112811 hasConceptScore W4381112811C120665830 @default.
• W4381112811 hasConceptScore W4381112811C121332964 @default.
• W4381112811 hasConceptScore W4381112811C124668440 @default.
• W4381112811 hasConceptScore W4381112811C125743686 @default.

• next