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• W4381122225 abstract "Site-specifically deuterated organocatalysts were prepared and found to show improved reactivity over the non-deuterated analogs. Two privileged C2 -symmetric chiral binaphthyl-modified tetraalkylammonium salts were selected for this study. The stability of these phase-transfer catalysts was generally improved by site-specific deuteration, though the degree of improvement was structure dependent. In particular, a large secondary kinetic isotope effect was observed for the tetradeuterated phase-transfer catalyst. The performance of these deuterated catalysts in the asymmetric catalytic alkylation of amino acid derivatives was better than that of non-deuterated analogs at low catalyst loadings. The results suggest that catalyst deuteration is a promising strategy for enhancing the stability and performance of organocatalysts." @default.
• W4381122225 created "2023-06-19" @default.
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• W4381122225 date "2023-07-28" @default.
• W4381122225 modified "2023-10-03" @default.
• W4381122225 title "Impact of Catalyst Deuteration on the Reactivity of Chiral Phase‐Transfer Organocatalysts" @default.
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• W4381122225 doi "https://doi.org/10.1002/chem.202301866" @default.
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