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- W4381136634 abstract "The selectivity in a group of oxazaborolidinium ion-catalysed reactions between aldehyde and diazo compounds cannot be explained using transition state theory. VRAI-selectivity, developed to predict the outcome of dynamically controlled reactions, can account for both the chemo- and the stereo-selectivity in these reactions, which are controlled by reaction dynamics. Subtle modifications to the substrate or catalyst substituents alter the potential energy surface, leading to changes in predominant reaction pathways and altering the barriers to the major product when reaction dynamics are considered. In addition, this study suggests an explanation for the mysterious inversion of enantioselectivity resulting from the inclusion of an ortho iPrO group in the catalyst." @default.
- W4381136634 created "2023-06-19" @default.
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- W4381136634 date "2023-06-19" @default.
- W4381136634 modified "2023-09-27" @default.
- W4381136634 title "Reaction dynamics as the missing puzzle piece: the origin of selectivity in oxazaborolidinium ion-catalysed reactions" @default.
- W4381136634 doi "https://doi.org/10.26434/chemrxiv-2023-74p0j" @default.
- W4381136634 hasPublicationYear "2023" @default.
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