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- W4381140678 abstract "Two new metal–organic frameworks based on highly flexible 1,4-diazabicyclo[2.2.2]octane N,N′-dioxide (odabco) ligands were successfully synthesized and characterized. Their crystallographic formulae are [M(DMF)2(odabco)2](ClO4)2·dioxane, where M2+ = Co2+ (1) and Ni2+ (2), and DMF is N,N-dimethylformamide. The title compounds possess cationic 2D coordination networks filled with perchlorate anions and dioxane solvent molecules in the interlayer space, with 20% solvent accessible volume. Carbon dioxide adsorption measurements for desolvated samples 1a and 2a gave 511 m2/g and 377 m2/g specific surface areas, respectively, revealing the first example of gas adsorption properties in the structure based on a flexible odabco bridge, despite the presence of large counteranions within the positively charged network. Magnetization measurements for 1, 1a, 2 and 2a reveal their paramagnetic nature to be in a reasonable agreement with crystal structures, and almost no solvent dependence of the magnetization characteristics. A decrease in the effective magnetic moment observed at low temperatures is attributed mostly to zero-field level-splitting in the octahedral Ni2+ and Co2+ ions." @default.
- W4381140678 created "2023-06-19" @default.
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- W4381140678 creator A5029443182 @default.
- W4381140678 creator A5062506391 @default.
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- W4381140678 date "2023-06-17" @default.
- W4381140678 modified "2023-09-26" @default.
- W4381140678 title "Flexible Co(II)-and Ni(II)-Based Cationic 2D Metal–Organic Frameworks Based on a Charge-Neutral (O,O)-Donor Bridge" @default.
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- W4381140678 cites W1997839570 @default.
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- W4381140678 cites W2021831710 @default.
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- W4381140678 cites W2030272204 @default.
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- W4381140678 cites W2038809098 @default.
- W4381140678 cites W2054779749 @default.
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- W4381140678 cites W2089325239 @default.
- W4381140678 cites W2103829561 @default.
- W4381140678 cites W2104383274 @default.
- W4381140678 cites W2105631122 @default.
- W4381140678 cites W2112362482 @default.
- W4381140678 cites W2114690061 @default.
- W4381140678 cites W2154043807 @default.
- W4381140678 cites W2160958792 @default.
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- W4381140678 cites W2466822843 @default.
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- W4381140678 cites W2909601537 @default.
- W4381140678 cites W2913624235 @default.
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- W4381140678 cites W3099997699 @default.
- W4381140678 cites W3118942482 @default.
- W4381140678 cites W3120519353 @default.
- W4381140678 cites W3133810957 @default.
- W4381140678 cites W3153483470 @default.
- W4381140678 cites W3155061067 @default.
- W4381140678 cites W3165538011 @default.
- W4381140678 cites W3184912591 @default.
- W4381140678 cites W3185238325 @default.
- W4381140678 cites W3212066890 @default.
- W4381140678 cites W4205609742 @default.
- W4381140678 cites W4211175509 @default.
- W4381140678 cites W4213029054 @default.
- W4381140678 cites W4224308530 @default.
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- W4381140678 doi "https://doi.org/10.3390/inorganics11060259" @default.
- W4381140678 hasPublicationYear "2023" @default.
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