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• W4381326366 abstract "A single crystal of Sr14.06Gd14.63(BO3)24 has been successfully grown through a high-temperature solution technique with K2O–KF–B2O3 as the flux. It crystallizes in the Pnma space group with parameters a = 22.3153(5) Å, b = 15.9087(4) Å, c = 8.7507(2) Å, and Z = 2. Sr14.06Gd14.63(BO3)24 has a three-dimensional (3D) framework built from [GdO] chains, in which the isolate [BO3]3– groups and Sr2+ ions fill in the space of the 3D framework. The magnetic measurements revealed that the title compound exhibits a large magnetocaloric effect with the magnetic entropy change of −ΔSm = 42.2 J kg–1 K–1 at 2 K for 7 T, which is higher than that of the commercial material, Gd3Ga5O12 (GGG), with −ΔSm of 38.4 J kg–1 K–1 under the same conditions. Moreover, the infrared spectrum (IR), UV–vis–NIR diffuse reflectance spectrum, and thermal stability were investigated." @default.
• W4381326366 created "2023-06-21" @default.
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• W4381326366 date "2023-06-20" @default.
• W4381326366 modified "2023-10-15" @default.
• W4381326366 title "Sr_14.06Gd_14.63(BO₃)₂₄: A Gadolinium-Rich Borate with Magnetic Refrigeration Performance" @default.
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• W4381326366 doi "https://doi.org/10.1021/acs.inorgchem.3c01060" @default.
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• W4381326366 hasPublicationYear "2023" @default.
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