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- W4381334504 abstract "Dilute-acid-soluble, complex rhodium oxides were generated in a molten K2CO3–K2O–B2O3–Al2O3 medium, and factors affecting their generation efficiency were investigated. Surface observation revealed that planar-shaped materials (the insoluble rhodium compounds) were covered by fine particles (the acid-soluble rhodium compounds) in the heat-treated rhodium. The fine particles contained Rh, K, Al, B, Ca, Si, and O. In contrast, the main components of the insoluble rhodium compounds were Rh, K, Al, Si, and O. Therefore, an efficient reaction of B and Ca with rhodium is an essential factor in solubilizing rhodium. The oxidation state of rhodium in the acid-soluble compounds was higher than that of the insoluble rhodium compounds, implying that efficient rhodium oxidation is another factor for rhodium solubilization. When air was supplied while synthesizing the rhodium compounds to enhance the oxidizing condition, rhodium extraction from the obtained heat-treated products increased to 74%." @default.
- W4381334504 created "2023-06-21" @default.
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- W4381334504 date "2023-09-01" @default.
- W4381334504 modified "2023-09-27" @default.
- W4381334504 title "Factors determining rhodium solubilization efficiency in molten K2CO3–K2O–B2O3–Al2O3 medium" @default.
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- W4381334504 doi "https://doi.org/10.1016/j.matchemphys.2023.128043" @default.
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