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- W4381431418 abstract "Magnesium electrolytes based on a polycarbonate with either magnesium tetrakis(hexafluoroisopropyloxy) borate (Mg(B(HFIP)4)2) or magnesium bis(trifluoromethanesulfonyl)imide (Mg(TFSI)2) for magnesium batteries were prepared and characterized. The side-chain-containing polycarbonate, poly(2-butyl-2-ethyltrimethylene carbonate) (P(BEC)), was synthesized by ring opening polymerization (ROP) of 5-ethyl-5-butylpropane oxirane ether carbonate (BEC) and mixed with Mg(B(HFIP)4)2 or Mg(TFSI)2 to form low- and high-salt-concentration polymer electrolytes (PEs). The PEs were characterized by impedance spectroscopy, differential scanning calorimetry (DSC), rheology, linear sweep voltammetry, cyclic voltammetry, and Raman spectroscopy. A transition from classical salt-in-polymer electrolytes to polymer-in-salt electrolytes was indicated by a significant change in glass transition temperature as well as storage and loss moduli. Ionic conductivity measurements indicated the formation of polymer-in-salt electrolytes for the PEs with 40 mol % Mg(B(HFIP)4)2 (HFIP40). In contrast, the 40 mol % Mg(TFSI)2 PEs showed mainly the classical behavior. HFIP40 was further found to have an oxidative stability window greater than 6 V vs Mg/Mg2+, but showed no reversible stripping-plating behavior in an Mg||SS cell." @default.
- W4381431418 created "2023-06-21" @default.
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- W4381431418 date "2023-06-20" @default.
- W4381431418 modified "2023-09-26" @default.
- W4381431418 title "Magnesium Polymer Electrolytes Based on the Polycarbonate Poly(2-butyl-2-ethyltrimethylene-carbonate)" @default.
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- W4381431418 doi "https://doi.org/10.1021/acsomega.3c00761" @default.
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