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- W4381470079 abstract "Spectroscopic characterization of neutral highly-coordinated compounds is essential in fundamental and applied research, but has been proven to be a challenging experimental target because of the difficulty in mass selection. Here, we report the preparation and size-specific infrared-vacuum ultraviolet (IR-VUV) spectroscopic identification of group-3 transition metal carbonyls Sc(CO)7 and TM(CO)8 (TM=Y, La) in the gas phase, which are the first confinement-free neutral heptacarbonyl and octacarbonyl complexes. The results indicate that Sc(CO)7 has a C2v structure and TM(CO)8 (TM=Y, La) have a D4h structure. Theoretical calculations predict that the formation of Sc(CO)7 and TM(CO)8 (TM=Y, La) is both thermodynamically exothermic and kinetically facile in the gas phase. These highly-coordinated carbonyls are 17-electron complexes when only those valence electrons that occupy metal−CO bonding orbitals are considered, in which the ligand-only 4b1u molecular orbital is ignored. This work opens new avenues toward the design and chemical control of a large variety of compounds with unique structures and properties." @default.
- W4381470079 created "2023-06-22" @default.
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- W4381470079 date "2023-07-04" @default.
- W4381470079 modified "2023-09-26" @default.
- W4381470079 title "Observation of Confinement‐Free Neutral Group Three Transition Metal Carbonyls Sc(CO)<sub>7</sub> and TM(CO)<sub>8</sub> (TM=Y, La)" @default.
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- W4381470079 doi "https://doi.org/10.1002/anie.202305490" @default.
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