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- W4381598678 abstract "The discovery of a new FeII oxalate framework of composition K2Fe[(C2O4)2(H2O)2]·0.18H2O is reported. Its crystal structure was solved by means of single crystal and powder X-ray diffraction. The new organic-inorganic hybrid compound crystallizes in the orthorhombic space group Pca21 with unit-cell parameters: a = 12.0351 (4) Å, b = 15.1265 (5) Å, c = 10.5562 (4) Å. This crystal structure, containing eight chemical formula, consists of a succession of FeO4(H2O)2 octahedra and K+ cations growing along b direction. Magnetization measurements indicate that the title compound is paramagnetic over the investigated temperature range (2-300 K). Both magnetization and 57Fe Mössbauer data indicate that Fe2+ is in a high-spin state." @default.
- W4381598678 created "2023-06-23" @default.
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- W4381598678 date "2023-06-22" @default.
- W4381598678 modified "2023-09-26" @default.
- W4381598678 title "Structure of the new iron(II) oxalate potassium salt K<sub>2</sub>Fe[(C<sub>2</sub>O<sub>4</sub>)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>]·0.18H<sub>2</sub>O" @default.
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- W4381598678 doi "https://doi.org/10.1107/s2052520623004602" @default.
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