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- W4381618461 abstract "Despite the C-H functionalization of arenes offering an efficient synthetic route towards functionalized aromatic compounds with high atom- and step-economy, the low reactivity of the C-H bond makes this transformation rather challenging. Compared with mono-metal catalysis, the introduction of bimetallic catalysis would greatly enhance the reactivity and selectivity of this transformation. In this review, we highlighted recent progress on C-H functionalization of arenes via NHC-Ni/Al catalysis. The added aluminum as a co-catalyst would activate arene through Lewis acid-base interaction, and regioselectivity could be controlled through the synergism of NHC-Ni and Al. And this strategy could be also applied in enantioselective C-H alkylation with well-designed chiral NHC ligands." @default.
- W4381618461 created "2023-06-23" @default.
- W4381618461 creator A5015327915 @default.
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- W4381618461 date "2023-06-21" @default.
- W4381618461 modified "2023-10-13" @default.
- W4381618461 title "C-H functionalization of arenes via NHC-supported Ni/Al bimetallic catalysis" @default.
- W4381618461 doi "https://doi.org/10.1055/a-2114-5508" @default.
- W4381618461 hasPublicationYear "2023" @default.
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