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- W4381618508 abstract "Halogenative annulation reactions of alkyne-tethered N- and O-containing arenes is a general strategy being employed in the construction of various halogenated N- and O-heterocycles. The methods are useful in producing valuable synthetic building blocks carrying C(sp2)-halide functional groups, which are useful synthetic handles, especially for cross-coupling reactions, and a myriad of other transformations. When the alkyne is tethered to the heteroatom via an aromatic ring, the reaction gives rise to aryl-fused halogenated heterocycles. In this Short Review, various past and present technologies of halogenative annulation methods to construct aryl-fused halogenated N- and O-heterocycles are examined with focus on more recent technologies, encompassing various participating roles of the halogenating agents. Additionally, future directions for this age-old, but still very useful, reactions will be considered." @default.
- W4381618508 created "2023-06-23" @default.
- W4381618508 creator A5036190061 @default.
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- W4381618508 date "2023-06-21" @default.
- W4381618508 modified "2023-09-25" @default.
- W4381618508 title "Halogenative Annulation Reactions of Alkyne-Tethered N- and O-Containing Arenes: Methods for Access to Aryl-Fused Halogenated N- and O-Heterocycles" @default.
- W4381618508 doi "https://doi.org/10.1055/a-2114-7582" @default.
- W4381618508 hasPublicationYear "2023" @default.
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