Matches in SemOpenAlex for { <https://semopenalex.org/work/W4381618800> ?p ?o ?g. }
Showing items 1 to 92 of
92
with 100 items per page.
- W4381618800 endingPage "116513" @default.
- W4381618800 startingPage "116513" @default.
- W4381618800 abstract "When cis- or trans-[PtCl2(NCtBu)2] was mixed with CuCl2 in MeOH under basic conditions, coordinated NCtBu was hydrolyzed to pivalamidate (piam) to capture Cu2+, accompanied by −OMe coordination and Cl− ion release. These mixing with cis-[PtCl2(NCtBu)2] and trans-[PtCl2(NCtBu)2] provided [{PtCu(piam)2}2(μ-OCH3)4] (1) and [{PtCu2(piam)2(OCH3)2}2(μ-OCH3)4] (2), which formed cyclic tetranuclear -Pt–Cu---Pt–Cu- and hexanuclear -Pt--Cu--Cu--Pt--Cu--Cu-, respectively. Several physical measurements revealed that the formal metal oxidation state in both 1 and 2 is +2, where the dx2–y2 unpaired electrons lie on the Cu2+ ions. Magnetic susceptibility measurements indicated that these unpaired electrons antiferromagnetically interact with neighboring electrons with 2J = −0.52 cm−1 for 1 and −26 cm−1 for 2." @default.
- W4381618800 created "2023-06-23" @default.
- W4381618800 creator A5077872426 @default.
- W4381618800 creator A5092234538 @default.
- W4381618800 date "2023-06-01" @default.
- W4381618800 modified "2023-09-25" @default.
- W4381618800 title "Structural and Magnetic Properties of Cyclic Tetranuclear or Hexanuclear Complexes Synthesized with [PtCl2(NC Bu)2] and CuCl2 under Basic Conditions" @default.
- W4381618800 cites W1554697240 @default.
- W4381618800 cites W177256982 @default.
- W4381618800 cites W1787540170 @default.
- W4381618800 cites W1892518122 @default.
- W4381618800 cites W1966182479 @default.
- W4381618800 cites W1969635440 @default.
- W4381618800 cites W1971503585 @default.
- W4381618800 cites W1984614201 @default.
- W4381618800 cites W1998243349 @default.
- W4381618800 cites W1999030522 @default.
- W4381618800 cites W2007106802 @default.
- W4381618800 cites W2008553568 @default.
- W4381618800 cites W2023271753 @default.
- W4381618800 cites W2024927936 @default.
- W4381618800 cites W2033618305 @default.
- W4381618800 cites W2078857325 @default.
- W4381618800 cites W2083182415 @default.
- W4381618800 cites W2094642658 @default.
- W4381618800 cites W2101160884 @default.
- W4381618800 cites W2143981217 @default.
- W4381618800 cites W2165122270 @default.
- W4381618800 cites W2171656282 @default.
- W4381618800 cites W2172451747 @default.
- W4381618800 cites W2326335602 @default.
- W4381618800 cites W2792894647 @default.
- W4381618800 cites W2797840747 @default.
- W4381618800 cites W2998528838 @default.
- W4381618800 cites W3006101222 @default.
- W4381618800 cites W3102409850 @default.
- W4381618800 cites W4200533938 @default.
- W4381618800 cites W4223487134 @default.
- W4381618800 doi "https://doi.org/10.1016/j.poly.2023.116513" @default.
- W4381618800 hasPublicationYear "2023" @default.
- W4381618800 type Work @default.
- W4381618800 citedByCount "0" @default.
- W4381618800 crossrefType "journal-article" @default.
- W4381618800 hasAuthorship W4381618800A5077872426 @default.
- W4381618800 hasAuthorship W4381618800A5092234538 @default.
- W4381618800 hasBestOaLocation W43816188001 @default.
- W4381618800 hasConcept C121332964 @default.
- W4381618800 hasConcept C145148216 @default.
- W4381618800 hasConcept C147120987 @default.
- W4381618800 hasConcept C16889073 @default.
- W4381618800 hasConcept C178790620 @default.
- W4381618800 hasConcept C185592680 @default.
- W4381618800 hasConcept C186927785 @default.
- W4381618800 hasConcept C199164860 @default.
- W4381618800 hasConcept C32909587 @default.
- W4381618800 hasConcept C544153396 @default.
- W4381618800 hasConcept C62520636 @default.
- W4381618800 hasConcept C71240020 @default.
- W4381618800 hasConcept C8010536 @default.
- W4381618800 hasConcept C94412978 @default.
- W4381618800 hasConceptScore W4381618800C121332964 @default.
- W4381618800 hasConceptScore W4381618800C145148216 @default.
- W4381618800 hasConceptScore W4381618800C147120987 @default.
- W4381618800 hasConceptScore W4381618800C16889073 @default.
- W4381618800 hasConceptScore W4381618800C178790620 @default.
- W4381618800 hasConceptScore W4381618800C185592680 @default.
- W4381618800 hasConceptScore W4381618800C186927785 @default.
- W4381618800 hasConceptScore W4381618800C199164860 @default.
- W4381618800 hasConceptScore W4381618800C32909587 @default.
- W4381618800 hasConceptScore W4381618800C544153396 @default.
- W4381618800 hasConceptScore W4381618800C62520636 @default.
- W4381618800 hasConceptScore W4381618800C71240020 @default.
- W4381618800 hasConceptScore W4381618800C8010536 @default.
- W4381618800 hasConceptScore W4381618800C94412978 @default.
- W4381618800 hasLocation W43816188001 @default.
- W4381618800 hasOpenAccess W4381618800 @default.
- W4381618800 hasPrimaryLocation W43816188001 @default.
- W4381618800 hasRelatedWork W1986244894 @default.
- W4381618800 hasRelatedWork W2009378376 @default.
- W4381618800 hasRelatedWork W2033905581 @default.
- W4381618800 hasRelatedWork W2065241619 @default.
- W4381618800 hasRelatedWork W2094710452 @default.
- W4381618800 hasRelatedWork W2274981864 @default.
- W4381618800 hasRelatedWork W2321039488 @default.
- W4381618800 hasRelatedWork W2347373460 @default.
- W4381618800 hasRelatedWork W2605876639 @default.
- W4381618800 hasRelatedWork W3094309621 @default.
- W4381618800 isParatext "false" @default.
- W4381618800 isRetracted "false" @default.
- W4381618800 workType "article" @default.