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- W4381664893 endingPage "10380" @default.
- W4381664893 startingPage "10380" @default.
- W4381664893 abstract "Vapor pressures and other thermodynamic properties of liquids, such as density and enthalpy of mixtures, are the key parameters in chemical engineering for designing new process units, and are also essential for understanding the physical chemistry, macroscopic and molecular behavior of fluid systems. In this work, vapor pressures between 278.15 and 323.15 K, densities and enthalpies of mixtures between 288.15 and 318.15 K for the binary mixture (2-propanol + 1,8-cineole) have been measured. From the vapor pressure data, activity coefficients and excess Gibbs energies were calculated via the Barker's method and the Wilson equation. Excess molar volumes and excess molar enthalpies were also obtained from the density and calorimetric measurements. Thermodynamic consistency test between excess molar Gibbs energies and excess molar enthalpies has been carried out using the Gibbs-Helmholtz equation. Robinson-Mathias, and Peng-Robinson-Stryjek-Vera together with volume translation of Peneloux equations of state (EoS) are considered, as well as the statistical associating fluid theory that offers a molecular vision quite suitable for systems having highly non-spherical or associated molecules. Of these three models, the first two fit the experimental vapor pressure results quite adequately; in contrast, only the last one approaches the volumetric behavior of the system. A brief comparison of the thermodynamic excess molar functions for binary mixtures of short-chain alcohol + 1,8-cineole (cyclic ether), or +di-n-propylether (lineal ether) is also included." @default.
- W4381664893 created "2023-06-23" @default.
- W4381664893 creator A5004366072 @default.
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- W4381664893 creator A5031927063 @default.
- W4381664893 creator A5073226378 @default.
- W4381664893 date "2023-06-20" @default.
- W4381664893 modified "2023-10-01" @default.
- W4381664893 title "Thermodynamic Behavior of (2-Propanol + 1,8-Cineole) Mixtures: Isothermal Vapor–Liquid Equilibria, Densities, Enthalpies of Mixing, and Modeling" @default.
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- W4381664893 doi "https://doi.org/10.3390/ijms241210380" @default.
- W4381664893 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37373528" @default.
- W4381664893 hasPublicationYear "2023" @default.
- W4381664893 type Work @default.