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- W4381682128 abstract "The effects of silver nanoparticles (NPs) embedded with samarium (Sm3+) ions doped on luminescence intensity of borate glasses was fabricated and evaluated using a method that is conventionally known as melt quenching. XRD study proved material's amorphousness. TEM examination determines average nanoparticle size distribution. Vibrational and structural units determined by FTIR and Raman spectra. DTA thermograms identify Tg, To, and Tp. XPS allows one to identify chemical shifts in addition to binding energies. Localized surface plasmon resonance (LSPR) band that has been identified is located at around 400 nm. It is a hypersensitive transition and enhancement of PL intensity due to the energy transfer from AgNPs to Sm3+ ions. A high-intensity emission peak can be seen at 599 nm (orange red), which is attributed to the electric dipole transition 4G5/2 6H7/2 of Sm3+ ions. The PL intensity non-linearity should be affected by the silver ion concentration. This happens because the energy is being transferred reverse, from the Sm3+ ions to the AgNPs, causing the PL intensity to oscillate in an anisotropic fashion. Analysis of the CIE diagram of glass system with Sm3+ ions suggests that it may be useful as a red luminous glass matrix in various photonic device implementations." @default.
- W4381682128 created "2023-06-23" @default.
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- W4381682128 date "2023-08-01" @default.
- W4381682128 modified "2023-09-23" @default.
- W4381682128 title "Silver nanoparticles doped heavy metal oxide borate glasses: luminescence and spectroscopic investigations" @default.
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- W4381682128 doi "https://doi.org/10.1016/j.optmat.2023.114017" @default.
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