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- W4381734207 abstract "Continuous-flow epoxidation of aliphatic and aromatic alkenes with hydrogen peroxide (H2O2) was carried out to give epoxides using a fixed-bed liquid flow reactor equipped with a solid titanium silicalite-1 (TS-1) catalyst column. The developed flow reaction enables continuous synthesis of 4-phenyl-1,2-epoxybutane from 4-phenyl-1-butene in 90%–98% yields (22.4 g) for 150 h from a catalyst column of 5 mm inner diameter with 100 mm length. Employment of a mixed solution of MeCN and MeOH with preservation of the Ti active site in TS-1 crystal structures with few defects permits continuous epoxidation of less-reactive long-chain terminal alkene and multifunctional alkene to give epoxides in 12%–98% yields with 78%–99% selectivity." @default.
- W4381734207 created "2023-06-24" @default.
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- W4381734207 date "2023-06-21" @default.
- W4381734207 modified "2023-10-16" @default.
- W4381734207 title "Continuous Synthesis of Epoxides from Alkenes by Hydrogen Peroxide with Titanium Silicalite‐1 Catalyst Using Flow Reactors" @default.
- W4381734207 doi "https://doi.org/10.1002/adsc.202300181" @default.
- W4381734207 hasPublicationYear "2023" @default.
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