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- W4381839181 abstract "We report a joint experimental and theoretical study on the reactivity of Agn+ clusters with H2S, D2O, and NH3. Complete dehydrogenation products are observed for Agn+ reacting with H2S, but no dehydrogenation products are found for D2O or NH3 under the same reaction condition. Theoretical calculations elucidate why Agn+ clusters show different reactivities with these inorganic hydrides. NH3 shows strong coordination with Agn+, but the dehydrogenation reactions are unfavorable; in contrast, the fragile H–S bonds and stable AgnS+ products facilitate the hydrogen evolution of H2S on Agn+. We fully analyzed the metal–ligand interactions of Agn+ clusters with three molecules and illustrated the reaction dynamics and charge-transfer interactions and altered the superatomic states during the formation of cluster sulfides. We expect this study to benefit the design of stable environmentally friendly desulfurization catalysts and also the understanding of the mechanism on ligand-protected metal clusters in wet chemistry." @default.
- W4381839181 created "2023-06-25" @default.
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- W4381839181 date "2023-06-23" @default.
- W4381839181 modified "2023-10-16" @default.
- W4381839181 title "What Determines If a Ligand Undergoes Coordination or Catalytic Activation on a Metal Cluster?" @default.
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- W4381839181 doi "https://doi.org/10.1021/acs.jpca.3c02784" @default.
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