Matches in SemOpenAlex for { <https://semopenalex.org/work/W4381849016> ?p ?o ?g. }
Showing items 1 to 69 of
69
with 100 items per page.
- W4381849016 abstract "Two pairs of cobalt(II) complexes with formulas of [Co(3,5,6-tcpa)(2,2’-bipy)Cl] (1A), [Co(3,5,6-tcpa)2(2,2’-bipy)]n (1B), [Co(3,5,6-tcpa)2(4,4’-bipy)(EtOH)]n (2A) and [Co(3,5,6-tcpa)2(4,4’-bipy)(EtOH)2]n (2B) have been cocrystallized by the solvothermal reaction of cobalt chloride hexahydrate with triclopyr (2-((3,5,6-trichloropyridin-2-yl) oxy)acetic acid, 3,5,6-Htcpa) and 2,2’-bipyridine (2,2’-bipy) or 4,4’-bipyridine (4,4’-bipy) coligands. Single-crystal X-ray diffraction analysis indicated that both 1A and 1B crystallized in triclinic system, space group P (no. 2). Compound 1A is mononuclear and 3,5,6-tcpa anion in it is a bidentate chelate ligand, while 1B is a 1D double-stranded chain structure in which 3,5,6-tcpa are bidentate bridging-μ2 linkers. In contrast, 2A has orthorhombic system, space group Aea 2(no. 41) and 2B showed monoclinic system, space group I2/a (no. 15). Complex 2A displays a 1D linear chain but 2B presents a zigzag chain, and 3,5,6-tcpa are both unidentate in them. The non-covalent interactions of Cl•••Cl/O halogen bonds, H•••O/Cl hydrogen bonds and/or π•••π stacking interactions play an important part in their crystal packing, which have been confirmed by the careful Hirshfeld surface analyses. It was proposed that flexible conformation alteration of 3,5,6-tcpa might be in charge of the cocrystallization phenomenon for 1A, 1B and 2A, 2B. The magnetic characterizations suggested antiferromagnetic coupling between neighbouring cobalt(II) centers both for 1B and 2B." @default.
- W4381849016 created "2023-06-25" @default.
- W4381849016 creator A5004365240 @default.
- W4381849016 creator A5009906998 @default.
- W4381849016 creator A5054659468 @default.
- W4381849016 creator A5063163223 @default.
- W4381849016 creator A5081789936 @default.
- W4381849016 creator A5089993758 @default.
- W4381849016 date "2023-06-25" @default.
- W4381849016 modified "2023-09-27" @default.
- W4381849016 title "One-pot cocrystallization of two pairs of cobalt(II) complexes based on flexible triclopyr and bipyridyl coligands: structural analyses, conformation comparison, non-covalent interactions and magnetic properties" @default.
- W4381849016 doi "https://doi.org/10.22541/au.168765892.26377536/v1" @default.
- W4381849016 hasPublicationYear "2023" @default.
- W4381849016 type Work @default.
- W4381849016 citedByCount "0" @default.
- W4381849016 crossrefType "posted-content" @default.
- W4381849016 hasAuthorship W4381849016A5004365240 @default.
- W4381849016 hasAuthorship W4381849016A5009906998 @default.
- W4381849016 hasAuthorship W4381849016A5054659468 @default.
- W4381849016 hasAuthorship W4381849016A5063163223 @default.
- W4381849016 hasAuthorship W4381849016A5081789936 @default.
- W4381849016 hasAuthorship W4381849016A5089993758 @default.
- W4381849016 hasBestOaLocation W43818490161 @default.
- W4381849016 hasConcept C112887158 @default.
- W4381849016 hasConcept C115624301 @default.
- W4381849016 hasConcept C116569031 @default.
- W4381849016 hasConcept C170493617 @default.
- W4381849016 hasConcept C178516000 @default.
- W4381849016 hasConcept C178790620 @default.
- W4381849016 hasConcept C185592680 @default.
- W4381849016 hasConcept C32909587 @default.
- W4381849016 hasConcept C33347731 @default.
- W4381849016 hasConcept C37243968 @default.
- W4381849016 hasConcept C42228675 @default.
- W4381849016 hasConcept C55493867 @default.
- W4381849016 hasConcept C61276311 @default.
- W4381849016 hasConcept C71240020 @default.
- W4381849016 hasConcept C8010536 @default.
- W4381849016 hasConceptScore W4381849016C112887158 @default.
- W4381849016 hasConceptScore W4381849016C115624301 @default.
- W4381849016 hasConceptScore W4381849016C116569031 @default.
- W4381849016 hasConceptScore W4381849016C170493617 @default.
- W4381849016 hasConceptScore W4381849016C178516000 @default.
- W4381849016 hasConceptScore W4381849016C178790620 @default.
- W4381849016 hasConceptScore W4381849016C185592680 @default.
- W4381849016 hasConceptScore W4381849016C32909587 @default.
- W4381849016 hasConceptScore W4381849016C33347731 @default.
- W4381849016 hasConceptScore W4381849016C37243968 @default.
- W4381849016 hasConceptScore W4381849016C42228675 @default.
- W4381849016 hasConceptScore W4381849016C55493867 @default.
- W4381849016 hasConceptScore W4381849016C61276311 @default.
- W4381849016 hasConceptScore W4381849016C71240020 @default.
- W4381849016 hasConceptScore W4381849016C8010536 @default.
- W4381849016 hasLocation W43818490161 @default.
- W4381849016 hasOpenAccess W4381849016 @default.
- W4381849016 hasPrimaryLocation W43818490161 @default.
- W4381849016 hasRelatedWork W15903973 @default.
- W4381849016 hasRelatedWork W1978638834 @default.
- W4381849016 hasRelatedWork W2026676565 @default.
- W4381849016 hasRelatedWork W2073959122 @default.
- W4381849016 hasRelatedWork W209031764 @default.
- W4381849016 hasRelatedWork W2093979529 @default.
- W4381849016 hasRelatedWork W2558618857 @default.
- W4381849016 hasRelatedWork W2902035643 @default.
- W4381849016 hasRelatedWork W2942835415 @default.
- W4381849016 hasRelatedWork W3023359194 @default.
- W4381849016 isParatext "false" @default.
- W4381849016 isRetracted "false" @default.
- W4381849016 workType "article" @default.