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- W4381895384 abstract "An efficient method is described for the first time for reductive aza-Claisen rearrangement of 1-(N-allylamino) anthraquinones to 1-amino-2-(prop-2?-enyl)anthraquinones using zinc powder in 1-methylimidazolium tetrafluoroborate ([Hmim] BF4) as an ionic liquid in good to excellent yields. Extending of this method on 1-(N-propargylamino)anthraquinones causes the production of 1,2,3,4-tetrahydronaphtho[2,3-h]quinoline-7,12-diones containing a newly synthesized six membered heterocyclic ring on anthraquinone core via performing this reductive [3,3] sigmatropic reaction followed by cyclization in a tandem manner. These rearrangements can be executed even in the presence of some other functional groups with excellent chemoselectivity." @default.
- W4381895384 created "2023-06-25" @default.
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- W4381895384 date "2023-01-01" @default.
- W4381895384 modified "2023-10-02" @default.
- W4381895384 title "Zinc-mediated efficient and selective reductive aza-Claisen rearrangement of N-allyland N-propargylaminoanthraquinones in ionic liquid" @default.
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- W4381895384 doi "https://doi.org/10.55730/1300-0527.3557" @default.
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