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- W4382021081 abstract "Sensitive disposable potentiometric sensors for determination of pioglitazone hydrochloride (PIO) have been constructed. The fabricated screen printed electrodes (SPEs) are based on multi-walled carbon nanotubes-polyvinyl chloride (MWNT-PVC) composite and crown ether as sensing ionophore. Electrode matrices compositions were optimized referring the effect of nature and content the sensing ionophore, anionic sites, plasticizer and nanomaterial. Detailed investigation revealed that sensors incorporated with 15-crown-5 ether as sensing ionophore, sodium tetrakis (4-florophenyl) borate (NaTFPB) as anionic site and 2-fluorophenyl 2-nitrophenyl ether (f-PNPE) as membrane plasticizer showed the best electroanalytical performances. The fabricated electrodes worked satisfactorily in the PIO concentration range from 10-6 to 10-2 mol L-1 with Nernstian compliance of 61.05±0.5 mV decade-1 and detection limit of 8×10-7 mol L-1. Carbon nanotubes remarkably improved the potential stability and lifetime of the fabricated sensors. The sensors have been successfully applied for the potentiometric determination of PIO in pharmaceutical preparations under batch experiments and flow injection analysis (FIA) with acceptable average recoveries. The relative simple fabrication protocol of disposable sensor, high sensitivity and stability of the method represents a promising approach for drug quality control laboratories." @default.
- W4382021081 created "2023-06-27" @default.
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- W4382021081 date "2015-03-01" @default.
- W4382021081 modified "2023-10-18" @default.
- W4382021081 title "Novel Pioglitazone Nanomaterial Based Screen Printed Sensors" @default.
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- W4382021081 doi "https://doi.org/10.1016/s1452-3981(23)04855-1" @default.
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