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- W4382021604 abstract "Ion-selective electrodes based on impregnated polymeric membranes now are used routinely for the monitoring of a wide variety of anions and cations. In this work, complexation of a macrocycle compound, derivative of diazatetrathia-18-crown-6 containing the 4,5-dithio-1,3-dithiole-2-thione unit, with some mono, di and trivalent metal ions was investigated by conductometric method. Since macrocycle was able to form a selective complex with Ho3+ ion (Kf=5.13± 0.22), it was applied as a sensing material in construction of a Ho3+ potentiometric membrane sensor. The response of proposed sensor was Nernstian across the concentration range of 1.0×10-6-1.0×10-2 mol L-1, while its response time was fast (~10s). The sensor potential response was not affected by the pH changes over the pH range of 4.5-9.0. The accuracy of the recommended electrode was tested by a Holmium ICP/DCP standard solution." @default.
- W4382021604 created "2023-06-27" @default.
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- W4382021604 date "2008-11-01" @default.
- W4382021604 modified "2023-09-23" @default.
- W4382021604 title "Lanthanide Recognition: A Ho3+ Potentiometric Membrane Sensor" @default.
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- W4382021604 doi "https://doi.org/10.1016/s1452-3981(23)15524-6" @default.
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