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- W4382021810 abstract "Polyaniline protected silver chloride nanoparticles based nanocomposite was synthesized by an interfacial polymerization method in which p-aminodiphenylamine was used as phase transfer agent as well as aniline source. The solid nanocomposite ([email protected]) was isolated and characterized with various instrumental methods such as FT-IR, SEM, EDAX and XRD techniques to understand size and shape and the nature of functional group. The electrocatalytic behavior of the [email protected] modified GCE was investigated towards the electrochemical oxidation of hydrazine in phosphate buffer medium and observed that a significant increases in peak current values at lower oxidation potential (+0.4 V vs. Ag wire). A calibration plot was constructed for the quantitative detection of hydrazine using DPV technique in the concentration ranges from 2-9 μM. The detection limit (3σ) for hydrazine was found to be 2.8 x 10-7 M. Similarly the electrocatalytic behaviour of polyaniline stabilised AgCl nanoparticles was also investigated on electrochemical reduction of hydrogen peroxide and shows an enhanced reduction current with lowering over potential (-0.75 V vs. Ag wire). Since the [email protected] modified GCE exhibit excellent electrocatalytic oxidation and reduction behaviour for the detection of both hydrazine and hydrogen peroxide, we have compared these results with the literature reported values. Hence the proposed system can be utilised for the detection of both hydrazine and hydrogen peroxide in various environmental samples at trace level." @default.
- W4382021810 created "2023-06-27" @default.
- W4382021810 creator A5003342366 @default.
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- W4382021810 date "2013-03-01" @default.
- W4382021810 modified "2023-10-10" @default.
- W4382021810 title "Single Pot Synthesis of Spherical Polyaniline Stabilized AgCl Nanoparticles by Interfacial Polymerization Method and Study Its Application on Electrochemical Detection of Hydrazine and Hydrogen peroxide" @default.
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- W4382021810 doi "https://doi.org/10.1016/s1452-3981(23)14462-2" @default.
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