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- W4382022016 abstract "A new greatly selective and sensitive PVC membrane sensor has been developed as a Tb3+ ion selective electrode, using an ionophore named 3-Hydroxybenzaldehyde azine (HBH). The best performance was obtained with a membrane composition of 30% poly(vinyl chloride), 66% nitrobenzen (NB), 2% HBH and 2% sodium tetraphenylborate (NaTPB). Fortunately, the benefits illustrated by the use of this sensor basically include a fast response time, lower detection limit, comparatively good selectivity with respect to alkali, alkaline earth, some transition, and heavy metal ions. The sensor works satisfactorily in the concentration range of 1.0×10-6 to 1.0×10-2 mol L-1 with detection limit of 8.3×10-7 mol L-1 and a Nernstian slope of 20.2±0.2 mV decade-1 of activity. This electrode showed a fast response time (~5 s). The proposed sensor was successfully applied as an indicator electrode for the potentiometric titration of a Tb3+ solution, with EDTA. It was also applied to the monitoring of terbium ion in various mixtures of different metal ions and the fluoride ion determination in some mouth washing solutions." @default.
- W4382022016 created "2023-06-27" @default.
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- W4382022016 date "2013-03-01" @default.
- W4382022016 modified "2023-09-25" @default.
- W4382022016 title "Evaluation and Characteristics of a Tb Electrochemical Sensor Based on Plasticized Poly(vinyl chloride) Membrane" @default.
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- W4382022016 doi "https://doi.org/10.1016/s1452-3981(23)14424-5" @default.
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