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- W4382022104 abstract "Composite NiP-RuO2/TiO2 coatings were deposited by simultaneous electroless codeposition of Ni-P metal matrix and mixtures of RuO2/TiO2 oxides on steel and brass substrates from a reducing solution in which particles were kept in suspension by stirring. Mixed oxides RuO2/TiO2 were prepared by thermal decomposition in air of a RuCl3/TiO2 suspension at 450 oC. Deposits were characterized by means of X-ray diffraction, scanning electron microscopy SEM, EDX and cyclic voltammetry. The obtained composite coatings exhibit the same morphology on both types of substrates. The electrocatalytic activity of the layers for hydrogen evolution reaction in 1M NaOH alkaline solution was determined by linear sweep technique with a slow sweep rate (v = 0.2 mV/s). Polarization curves recorded on mixed oxide reinforced Ni-P electrodes show a unique Tafel slope of approximately 120mV/dec in the whole potential range (–1.1/-1.5 V vs. SCE), while polarization curves obtained on NiP-RuO2 composite coatings are bent with Tafel slopes of about 90 mV/dec at low current densities and 200 mV/dec at higher current densities. NiP-RuO2/TiO2 electrode activity increases with RuO2, thus NiP-RuO2 electrode showing the highest activities on both types of substrates." @default.
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- W4382022104 date "2013-03-01" @default.
- W4382022104 modified "2023-10-16" @default.
- W4382022104 title "Electrocatalytic Properties of Electroless NiP- RuO2/TiO2 Composite Coatings" @default.
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- W4382022104 doi "https://doi.org/10.1016/s1452-3981(23)14417-8" @default.
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