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- W4382022647 abstract "In this paper, hierarchical and high-rough PtZn alloy films were cathodically fabricated from a smooth Pt substrate in an alkaline aqueous solution of low ZnSO4 concentration at a moderate temperature of 40 oC. Subsequently, the Pt/Zn atomic ratios for the films were regulated by dissolution of bulk Zn and partial dealloying of alloyed Zn in a H2SO4 solution under lower and higher anodic potentials, respectively. The films were characterized by scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and X-ray photoelectron spectroscopy (XPS). The film formation might be closely related to processes including Zn electrodeposition, PtZn alloying, hydrogen evolution and cathodic corrosion of Pt under highly cathodic polarization. The as-prepared films exhibit better electrocatalytic activities toward the oxidation of formic acid and methanol, as compared with smooth Pt and PtZn films prepared under less cathodic polarization (without hydrogen evolution)." @default.
- W4382022647 created "2023-06-27" @default.
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- W4382022647 date "2012-04-01" @default.
- W4382022647 modified "2023-10-11" @default.
- W4382022647 title "Formation of Hierarchical PtZn Alloy Films under Highly Cathodic Polarization of Pure Pt in a Dilute ZnSO4 Solution and Their Electrocatalytic Applications" @default.
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- W4382022647 doi "https://doi.org/10.1016/s1452-3981(23)13952-6" @default.
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