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- W4382022985 abstract "PtSn/C, PtSn/Er2O3-C, PtSn/CeO2–C, PtSn/La2O3–C and PtSn/Nd2O3–C electrocatalysts were prepared by an alcohol-reduction process using H2PtCl6.6H2O and SnCl2.2H2O as metal sources, ethylene glycol as solvent and reducing agent, 85% Vulcan XC72-15% rare earth (Er2O3, CeO2, La2O3 and Nd2O3) as support. The platinum and tin metal loadings were always kept at 20 wt%. The electrocatalysts were characterized by EDX, XRD and TEM, while that the performance for ethanol oxidation was investigated by cyclic voltammetry and cronoamperommetry at room temperature. The PtSn/Er2O3–C electrocatalyst showed an increase of performance for ethanol oxidation in relation to PtSn/C electrocatalyst. The final current values after holding the cell potential at 0.5 V versus RHE for 30 min were the following: PtSn/Er2O3–C > PtSn/CeO2–C > PtSn/Nd2O3–C > PtSn/La2O3–C > PtSn/C. In the tests at 100oC on a single cell of a direct ethanol fuel cell (DEFC), the PtSn/Er2O3–C electrocatalyst also showed the best performance in relation to the others electrocatalysts." @default.
- W4382022985 created "2023-06-27" @default.
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- W4382022985 date "2010-12-01" @default.
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- W4382022985 title "Preparation and Characterization of PtSn/C-Rare Earth Using an Alcohol Reduction Process for Ethanol Electro-Oxidation" @default.
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- W4382022985 doi "https://doi.org/10.1016/s1452-3981(23)15391-0" @default.
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