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- W4382023164 abstract "SBA-15 channels was modified by aluminum complex of 8-hydroxyquinoline. The new synthesized nano-material had a selective interaction with dichromate ions which was studied by fluorescence spectroscopy. A new modified SBA-15 was then used in making a new dichromate nano-composite carbon paste electrode. Since carbon paste electrode based on MWCNTs and RTILs show better performance in comparison with traditional carbon paste electrodes, the electrode was composed of 5% Multi-walled Carbon Nanotube (MWCNT), 55% graphite powder, 20% room temperature ionic liquid (RTIL) and 20% modified SBA-15. MWCNT in the composition of the paste improve the dynamic working range, detection limit, response time, lifetime, and stability of the nano-composite sensor due to its high conductivity. Replacement of paraffin oil with RTIL improved the sensitivity of the sensor from a near-Nernstian slope to Nernstian one. The sensor worked well with a Nernstian response of -28.6±0.3 mV decade-1 of Cr2O72- anion in a wide dynamic concentration range of 1.0×10-6-1.0×10-1 M. The electrode had relatively short response time (about 23 s), and it was found to produce stable responses for more than 8 weeks." @default.
- W4382023164 created "2023-06-27" @default.
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- W4382023164 date "2012-03-01" @default.
- W4382023164 modified "2023-10-14" @default.
- W4382023164 title "Dichromate Ion-selective Sensor Based on Functionalized SBA-15/ Ionic Liquid/MWCNTs/Graphite" @default.
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- W4382023164 doi "https://doi.org/10.1016/s1452-3981(23)13849-1" @default.
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