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- W4382023251 abstract "Zinc-sulfur nanocomposite is prepared by using, zinc chloride (0.07 M), and sodium thiosulfate (0.09 M) as precursors in HCl solution with adjusted pH=1 by the pulsed current of 200 mA.cm-2 with a frequency of 18 Hz at 0°C. The morphology, the particles sizes, and the composition of each synthesized sample are studied by SEM and XRD. The zinc-sulfur nanocomposite synthesized in optimum conditions includes halo-nanospheres with an average thickness of 50 nm. The sulfur content of the samples is increased when the synthesis temperature is increased. The sample synthesized at 0 °C with low sulfur content (~25%wt) was used as negative (anode) material of rechargeable alkaline zinc-manganese dioxide (RAM) batteries. Some samples are synthesized in the absence of thiosulfate to form nanostructured zinc powder. The performance of zinc-sulfur nanocomposite as negative materials of RAM batteries is compared with those of commercial zinc powder and pure nanostructured zinc powder. The battery tests are shown a discharge capacity 300 mA.h.g-1 for zinc-sulfur nanocomposite at first discharges (near to pure nanostructured zinc), but the cycle-life test showed that the zinc-sulfur nanocomposite has a longer cycle-life than the others do." @default.
- W4382023251 created "2023-06-27" @default.
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- W4382023251 date "2012-03-01" @default.
- W4382023251 modified "2023-09-27" @default.
- W4382023251 title "Pulse Galvanostatic Synthesis of Zinc-Sulfur Nanocomposites and Application as a Novel Negative Material of Rechargeable Zinc-Manganese Dioxide Alkaline Batteries" @default.
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- W4382023251 doi "https://doi.org/10.1016/s1452-3981(23)13865-x" @default.
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